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Register a new userPlasmonic-based gas sensing with graphene nanoribbons
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The main challenge to exploiting plasmons for gas vibrational mode sensing is the extremely weak infrared absorption of gas species. In this work, we explore the possibility of trapping free gas molecules via surface adsorption, optical, or electrostatic fields to enhance gas-plasmon interactions and to increase plasmon sensing ability. We discuss the relative strengths of these trapping forces and found gas adsorption in a typical nanoribbon array plasmonic setup produces measurable dips in optical extinction of magnitude 0.1 % for gas concentration of about parts per thousand level.
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Based on first-principles calculations we predict that periodically repeated junctions of armchair graphene nanoribbons of different widths form superlattice structures. In these superlattice heterostructures the width and the energy gap are modulated in real space and specific states are confined in certain segments. Orientation of constituent nanoribbons, their width and length, the symmetry of the junction are the structural parameters to engineer electronic properties of these quantum structures. Not only the size modulation, but also composition modulation, such as periodically repeated, commensurate heterojunctions of BN and graphene honeycomb nanoribbons result in a multiple quantum well structure. We showed that these graphene based quantum structures can introduce novel concepts to design nanodevices.
In this work we study thermoelectric properties of graphene nanoribbons with side-attached organic molecules. By adopting a single-band tight binding Hamiltonian and the Greens function formalism, we calculated the transmission and Seebeck coefficients for different hybrid systems. The corresponding thermopower profiles exhibit a series of sharp peaks at the eigenenergies of the isolated molecule. We study the effects of the temperature on the thermoelectric response, and we consider random configurations of molecule distributions, in different disorder regimes. The main characteristics of the thermopower are not destroyed under temperature and disorder, indicating the robustness of the system as a proposed molecular thermo-sensor device.
Chemical vapor deposited graphene is nanopatterned by a spherical block-copolymer etch mask. The use of spherical rather than cylindrical block copolymers allows homogeneous patterning of cm-scale areas without any substrate surface treatment. Raman spectroscopy was used to study the controlled generation of point defects in the graphene lattice with increasing etching time, confirming that alongside the nanomesh patterning, the nanopatterned CVD graphene presents a high defect density between the mesh holes. The nanopatterned samples showed sensitivities for NO2 of more than one order of magnitude higher than for non-patterned graphene. NO2 concentrations as low as 300 ppt were detected with an ultimate detection limit of tens of ppt. This is so far the smallest value reported for not UV illuminated graphene chemiresistive NO2 gas sensors. The drastic improvement in the gas sensitivity is believed to be due to the high adsorption site density, thanks to the combination of edge sites and point defect sites. This work opens the possibility of large area fabrication of nanopatterned graphene with extreme density of adsorption sites for sensing applications.
We study the conductance through two types of graphene nanostructures: nanoribbon junctions in which the width changes from wide to narrow, and curved nanoribbons. In the wide-narrow structures, substantial reflection occurs from the wide-narrow interface, in contrast to the behavior of the much studied electron gas waveguides. In the curved nanoribbons, the conductance is very sensitive to details such as whether regions of a semiconducting armchair nanoribbon are included in the curved structure -- such regions strongly suppress the conductance. Surprisingly, this suppression is not due to the band gap of the semiconducting nanoribbon, but is linked to the valley degree of freedom. Though we study these effects in the simplest contexts, they can be expected to occur for more complicated structures, and we show results for rings as well. We conclude that experience from electron gas waveguides does not carry over to graphene nanostructures. The interior interfaces causing extra scattering result from the extra effective degrees of freedom of the graphene structure, namely the valley and sublattice pseudospins.
A pseudo-magnetic field kink can be realized along a graphene nanoribbon using strain engineering. Electron transport along this kink is governed by snake states that are characterized by a single propagation direction. Those pseudo-magnetic fields point towards opposite directions in the K and K valleys, leading to valley polarized snake states. In a graphene nanoribbon with armchair edges this effect results in a valley filter that is based only on strain engineering. We discuss how to maximize this valley filtering by adjusting the parameters that define the stress distribution along the graphene ribbon.
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