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Register a new userMaxwells demon and the management of ignorance in stochastic thermodynamics
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Authors
Ian J. Ford
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It is nearly 150 years since Maxwell challenged the validity of the second law of thermodynamics by imagining a tiny creature who could sort the molecules of a gas in such a way that would decrease entropy without exerting any work. The demon has been discussed largely using thought experiments, but it has recently become possible to exert control over nanoscale systems, just as Maxwell imagined, and the status of the second law has become a more practical matter, raising the issue of how measurements manage our ignorance in a way that can be exploited. The framework of stochastic thermodynamics extends macroscopic concepts such as heat, work, entropy and irreversibility to small systems and allows us explore the matter. Some arguments against a successful demon imply a second law that can be suspended indefinitely until we dissipate energy in order to remove the records of his operations. In contrast, under stochastic thermodynamics the demon fails because on average more work is performed upfront in making a measurement than is to be extracted by exploiting the outcome. This requires us to exclude systems and a demon that evolve under what might be termed self-sorting dynamics, and we reflect on the constraints on control that this implies while still working within a thermodynamic framework.
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The first direct experimental replication of the Maxwell Demon thought experiment is outlined. The experiment determines the velocity/kinetic energy distribution of the particles in a sample by a novel interpretation of the results from a standard time-of-flight (TOF) small angle neutron scattering (SANS) procedure. Perspex at 293 K was subjected to neutrons at 82.2 K. The key result is a TOF velocity distribution curve that is a direct spatial and time-dependent microscopic probe of the velocity distribution of the Perspex nuclei at 293 K. Having this curve, one can duplicate the Demons approach by selecting neutrons at known kinetic energies. One example is given: namely, two reservoirs -- hot and cold reservoirs -- were generated from the 293 K source without disturbing its original 293 K energy distribution.
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