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Register a new userFormation of Charons Red Poles From Seasonally Cold-Trapped Volatiles
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A unique feature of Plutos large satellite Charon is its dark red northern polar cap. Similar colours on Plutos surface have been attributed to organic macromolecules produced by energetic radiation processing of hydrocarbons. The polar location of this material on Charon implicates the temperature extremes that result from Charons high obliquity and long seasons. The escape of Plutos atmosphere provides a potential feed stock for production of complex chemistry. Gas from Pluto that is transiently cold-trapped and processed at Charons winter pole was proposed as an explanation on the basis of an image of Charons northern hemisphere, but not modelled quantitatively. Here we report images of the southern hemisphere illuminated by Pluto-shine and also images taken during the approach phase showing the northern polar cap over a range of longitudes. We model the surface thermal environment on Charon, the supply and temporary cold-trapping of material escaping from Pluto, and, while cold-trapped, its photolytic processing into more complex and less volatile molecules. The model results are consistent with the proposed mechanism producing the observed colour pattern on Charon.
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We present the first measurements of Charons far-ultraviolet surface reflectance, obtained by the Alice spectrograph on New Horizons. We find no measurable flux shortward of 1650 A, and Charons geometric albedo is $<0.019$ ($3sigma$) at 1600 A. From 1650--1725 A Charons geometric albedo increases to $0.166pm0.068$, and remains nearly constant until 1850 A. As this spectral shape is characteristic of H$_2$O ice absorption, Charon is the first Kuiper belt object with a H$_2$O ice surface to be detected in the far-ultraviolet. Charons geometric albedo is $sim3.7$ times lower than Enceladus at these wavelengths, but has a very similar spectral shape. We attribute this to similarities in their surface compositions, and the difference in absolute reflectivity to a high concentration or more-absorbing contaminants on Charons surface. Finally, we find that Charon has different solar phase behavior in the FUV than Enceladus, Mimas, Tethys, and Dione, with a stronger opposition surge than Enceladus and a shallower decline at intermediate solar phase angles than any of these Saturnian satellites.
Volatiles are compounds with low sublimation temperatures, and they make up most of the condensible mass in typical planet-forming environments. They consist of relatively small, often hydrogenated, molecules based on the abundant elements carbon, nitrogen and oxygen. Volatiles are central to the process of planet formation, forming the backbone of a rich chemistry that sets the initial conditions for the formation of planetary atmospheres, and act as a solid mass reservoir catalyzing the formation of planets and planetesimals. This growth has been driven by rapid advances in observations and models of protoplanetary disks, and by a deepening understanding of the cosmochemistry of the solar system. Indeed, it is only in the past few years that representative samples of molecules have been discovered in great abundance throughout protoplanetary disks - enough to begin building a complete budget for the most abundant elements after hydrogen and helium. The spatial distributions of key volatiles are being mapped, snow lines are directly seen and quantified, and distinct chemical regions within protoplanetary disks are being identified, characterized and modeled. Theoretical processes invoked to explain the solar system record are now being observationally constrained in protoplanetary disks, including transport of icy bodies and concentration of bulk condensibles. The balance between chemical reset - processing of inner disk material strong enough to destroy its memory of past chemistry, and inheritance - the chemically gentle accretion of pristine material from the interstellar medium in the outer disk, ultimately determines the final composition of pre-planetary matter. This chapter focuses on making the first steps toward understanding whether the planet formation processes that led to our solar system are universal.
Planetary embryos form protoplanets via mutual collisions, which can lead to the development of magma oceans. During their solidification, large amounts of the mantles volatile contents may be outgassed. The resulting H$_2$O/CO$_2$ dominated steam atmospheres may be lost efficiently via hydrodynamic escape due to the low gravity and the high stellar EUV luminosities. Protoplanets forming later from such degassed building blocks could therefore be drier than previously expected. We model the outgassing and subsequent hydrodynamic escape of steam atmospheres from such embryos. The efficient outflow of H drags along heavier species (O, CO$_2$, noble gases). The full range of possible EUV evolution tracks of a solar-mass star is taken into account to investigate the escape from Mars-sized embryos at different orbital distances. The envelopes are typically lost within a few to a few tens of Myr. Furthermore, we study the influence on protoplanetary evolution, exemplified by Venus. We investigate different early evolution scenarios and constrain realistic cases by comparing modeled noble gas isotope ratios with observations. Starting from solar values, consistent isotope ratios (Ne, Ar) can be found for different solar EUV histories, as well as assumptions about the initial atmosphere (either pure steam or a mixture with accreted H). Our results generally favor an early accretion scenario with a small amount of accreted H and a low-activity Sun, because in other cases too much CO$_2$ is lost during evolution, which is inconsistent with Venus present atmosphere. Important issues are likely the time at which the initial steam atmosphere is outgassed and/or the amount of CO$_2$ which may still be delivered at later evolutionary stages. A late accretion scenario can only reproduce present isotope ratios for a highly active young Sun, but then very massive steam atmospheres would be required.
We aim to determine the production rates of several parent and product volatiles and the 12C/13C isotopic carbon ratio in the long-period comet C/2004 Q2 (Machholz), which is likely to originate from the Oort Cloud. The line emission from several molecules in the coma was measured with high signal-to-noise ratio in January 2005 at heliocentric distance of 1.2 AU by means of high-resolution spectroscopic observations using the Submillimeter Telescope (SMT). We have obtained production rates of several volatiles (CH3OH, HCN, H13CN, HNC, H2CO, CO and CS) by comparing the observed and simulated line-integrated intensities. Furthermore, multiline observations of the CH3OH (7-6) series allow us to estimate the rotational temperature using the rotation diagram technique. We find that the CH3OH population distribution of the levels sampled by these lines can be described by a rotational temperature of 40 pm 3 K. Derived mixing ratios relative to hydrogen cyanide are CO/CH3OH/H2CO/CS/HNC/H13CN/HCN = 30.9/24.6/4.8/0.57/0.031/0.013/1 assuming a pointing offset of 8 due to the uncertain ephemeris at the time of the observations and the telescope pointing error. The measured relative molecular abundances in C/2004 Q2 (Machholz) are between low- to typical values of those obtained in Oort Cloud comets, suggesting that it has visited the inner solar system previously and undergone thermal processing. The HNC/HCN abundance ratio of ~3.1% is comparable to that found in other comets, accounting for the dependence on the heliocentric distance, and could possibly be explained by ion-molecule chemical processes in the low-temperature atmosphere. From a tentative H13CN detection, the measured value of 97 pm 30 for the H12CN/H13CN isotopologue pair is consistent with a telluric value.
Water is fundamental to our understanding of the evolution of planetary systems and the delivery of volatiles to the surfaces of potentially habitable planets. Yet, we currently have essentially no facilities capable of observing this key species comprehensively. With this white paper, we argue that we need a relatively large, cold space-based observatory equipped with a high-resolution spectrometer, in the mid- through far-infrared wavelength range (25-600~$mu$m) in order to answer basic questions about planet formation, such as where the Earth got its water, how giant planets and planetesimals grow, and whether water is generally available to planets forming in the habitable zone of their host stars.
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