No Arabic abstract
From the perspective of quantum thermodynamics, realisable measurements cost work and result in measurement devices that are not perfectly correlated with the measured systems. We investigate the consequences for the estimation of work in non-equilibrium processes and for the fundamental structure of the work fluctuations when one assumes that the measurements are non-ideal. We show that obtaining work estimates and their statistical moments at finite work cost implies an imperfection of the estimates themselves: more accurate estimates incur higher costs. Our results provide a qualitative relation between the cost of obtaining information about work and the trustworthiness of this information. Moreover, we show that Jarzynskis equality can be maintained exactly at the expense of a correction that depends only on the systems energy scale, while the more general fluctuation relation due to Crooks no longer holds when the cost of the work estimation procedure is finite. We show that precise links between dissipation and irreversibility can be extended to the non-ideal situation.
We calculate the first two moments and full probability distribution of the work performed on a system of bosonic particles in a two-mode Bose-Hubbard Hamiltonian when the self-interaction term is varied instantaneously or with a finite-time ramp. In the instantaneous case, we show how the irreversible work scales differently depending on whether the system is driven to the Josephson or Fock regime of the bosonic Josephson junction. In the finite-time case, we use optimal control techniques to substantially decrease the irreversible work to negligible values. Our analysis can be implemented in present-day experiments with ultracold atoms and we show how to relate the work statistics to that of the population imbalance of the two modes.
One of the most fundamental tasks in quantum thermodynamics is extracting energy from one system and subsequently storing this energy in an appropriate battery. Both of these steps, work extraction and charging, can be viewed as cyclic Hamiltonian processes acting on individual quantum systems. Interestingly, so-called passive states exist, whose energy cannot be lowered by unitary operations, but it is safe to assume that the energy of any not fully charged battery may be increased unitarily. However, unitaries raising the average energy by the same amount may differ in qualities such as their precision, fluctuations, and charging power. Moreover, some unitaries may be extremely difficult to realize in practice. It is hence of crucial importance to understand the qualities that can be expected from practically implementable transformations. Here, we consider the limitations on charging batteries when restricting to the feasibly realizable family of Gaussian unitaries. We derive optimal protocols for general unitary operations as well as for the restriction to easier implementable Gaussian unitaries. We find that practical Gaussian battery charging, while performing significantly less well than is possible in principle, still offers asymptotically vanishing relative charge variances and fluctuations.
We discuss thermodynamic work cost of various stages of a quantum estimation protocol: probe and memory register preparation, measurement and extraction of work from post-measurement states. We consider both (i) a multi-shot scenario, where average work is calculated in terms of the standard Shannon entropy and (ii) a single-shot scenario, where deterministic work is expressed in terms of min- and max-entropies. We discuss an exemplary phase estimation protocol where estimation precision is optimized under a fixed work credit (multi-shot) or a total work cost (single-shot). In the multi-shot regime precision is determined using the concept of Fisher information, while in the single-shot case we advocate the use of confidence intervals as only they can provide a meaningful and reliable information in a single-shot experiment, combining naturally with the the concept of deterministic work.
We consider work extraction from $N$ copies of a quantum system. When the same work-extraction process is implemented on each copy, the relative size of fluctuations is expected to decay as $1/sqrt{N}$. Here, we consider protocols where the copies can be processed collectively, and show that in this case work fluctuations can disappear exponentially fast in $N$. As a consequence, a considerable proportion of the average extractable work $mathcal{W}$ can be obtained almost deterministically by globally processing a few copies of the state. This is derived in the two canonical scenarios for work extraction: (i) in thermally isolated systems, where $mathcal{W}$ corresponds to the energy difference between initial and passive states, known as the ergotropy, and (ii) in the presence of a thermal bath, where $mathcal{W}$ is given by the free energy difference between initial and thermal states.
When engineering microscopic machines, increasing efficiency can often come at a price of reduced reliability due to the impact of stochastic fluctuations. Here we develop a general method for performing multi-objective optimisation of efficiency and work fluctuations in thermal machines operating close to equilibrium in either the classical or quantum regime. Our method utilises techniques from thermodynamic geometry, whereby we match optimal solutions to protocols parameterised by their thermodynamic length. We characterise the optimal protocols for continuous-variable Gaussian machines, which form a crucial class in the study of thermodynamics for microscopic systems.