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Register a new userMARVEL Analysis of the Measured High-Resolution Rovibronic Spectra of 90Zr16O
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Zirconium oxide(ZrO) is an important astrophysical molecule that defines the S-star classification class for cool giant stars. Accurate, empirical rovibronic energy levels, with associated labels and uncertainties, are reported for 9 low-lying electronic states of the diatomic 90Zr16O molecule. These 8088 empirical energy levels are determined using the Marvel (Measured Active Rotational-Vibrational Energy Levels) algorithm with 23 317 input assigned transition frequencies, 22 549 of which were validated. A temperature-dependent partition function is presented alongside updated spectroscopic constants for the 9 low-lying electronic states.
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The calcium monohydroxide radical (CaOH) is an important astrophysical molecule relevant to cool stars and rocky exoplanets, amongst other astronomical environments. Here, we present a consistent set of highly accurate rovibronic (rotation-vibration-electronic) energy levels for the five lowest electronic states ($tilde{X},^2Sigma^+$, $tilde{A},^2Pi$, $tilde{B},^2Sigma^+$, $tilde{C},^2Delta$, $tilde{D},^2Sigma^+$) of CaOH. A comprehensive analysis of the published spectroscopic literature on this system has allowed 1955 energy levels to be determined from 3204 rovibronic experimental transitions, all with unique quantum number labelling and measurement uncertainties. The dataset covers rotational excitation up to $J=62.5$ for molecular states below 29,000~cm$^{-1}$. The analysis was performed using the MARVEL algorithm, which is a robust procedure based on the theory of spectroscopic networks. The dataset provided will significantly aid future interstellar, circumstellar and atmospheric detections of CaOH, as well as assisting in the design of efficient laser cooling schemes in ultracold molecule research and precision tests of fundamental physics.
We investigated the reliability of our silicon atomic model and the influence of non-local thermodynamical equilibrium (NLTE) on the formation of neutral silicon (Si I) lines in the near-infrared (near-IR) H-band. We derived the differential Si abundances for 13 sample stars with high-resolution H-band spectra from the Apache Point Observatory Galactic Evolution Experiment (APOGEE), as well as from optical spectra, both under local thermodynamical equilibrium (LTE) and NLTE conditions. We found that the differences between the Si abundances derived from the H-band and from optical lines for the same stars are less than 0.1 dex when the NLTE effects included, and that NLTE reduces the line-to-line scatter in the H-band spectra for most sample stars. These results suggest that our Si atomic model is appropriate for studying the formation of H-band Si lines. Our calculations show that the NLTE corrections of the Si I H-band lines are negative, i.e. the final Si abundances will be overestimated in LTE. The corrections for strong lines depend on surface gravity, and tend to be larger for giants, reaching ~ -0.2 dex in our sample, and up to ~ -0.4 dex in extreme cases of APOGEE targets. Thus, the NLTE effects should be included in deriving silicon abundances from H-band Si I lines, especially for the cases where only strong lines are available.
Aiming at testing the validity of our magnesium atomic model and investigating the effects of non-local thermodynamical equilibrium (NLTE) on the formation of the H-band neutral magnesium lines, we derive the differential Mg abundances from selected transitions for 13 stars either adopting or relaxing the assumption of local thermodynamical equilibrium (LTE). Our analysis is based on high-resolution and high signal-to-noise ratio H-band spectra from the Apache Point Observatory Galactic Evolution Experiment (APOGEE) and optical spectra from several instruments. The absolute differences between the Mg abundances derived from the two wavelength bands are always less than 0.1 dex in the NLTE analysis, while they are slightly larger for the LTE case. This suggests that our Mg atomic model is appropriate for investigating the NLTE formation of the H-band Mg lines. The NLTE corrections for the Mg I H-band lines are sensitive to the surface gravity, becoming larger for smaller log g values, and strong lines are more susceptible to departures from LTE. For cool giants, NLTE corrections tend to be negative, and for the strong line at 15765 AA they reach -0.14 dex in our sample, and up to -0.22 dex for other APOGEE stars. Our results suggest that it is important to include NLTE corrections in determining Mg abundances from the H-band Mg I transitions, especially when strong lines are used.
The Gaia-ESO Survey is obtaining high-quality spectroscopic data for about 10^5 stars using FLAMES at the VLT. UVES high-resolution spectra are being collected for about 5000 FGK-type stars. These UVES spectra are analyzed in parallel by several state-of-the-art methodologies. Our aim is to present how these analyses were implemented, to discuss their results, and to describe how a final recommended parameter scale is defined. We also discuss the precision (method-to-method dispersion) and accuracy (biases with respect to the reference values) of the final parameters. These results are part of the Gaia-ESO 2nd internal release and will be part of its 1st public release of advanced data products. The final parameter scale is tied to the one defined by the Gaia benchmark stars, a set of stars with fundamental atmospheric parameters. A set of open and globular clusters is used to evaluate the physical soundness of the results. Each methodology is judged against the benchmark stars to define weights in three different regions of the parameter space. The final recommended results are the weighted-medians of those from the individual methods. The recommended results successfully reproduce the benchmark stars atmospheric parameters and the expected Teff-log g relation of the calibrating clusters. Atmospheric parameters and abundances have been determined for 1301 FGK-type stars observed with UVES. The median of the method-to-method dispersion of the atmospheric parameters is 55 K for Teff, 0.13 dex for log g, and 0.07 dex for [Fe/H]. Systematic biases are estimated to be between 50-100 K for Teff, 0.10-0.25 dex for log g, and 0.05-0.10 dex for [Fe/H]. Abundances for 24 elements were derived: C, N, O, Na, Mg, Al, Si, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Mo, Ba, Nd, and Eu. The typical method-to-method dispersion of the abundances varies between 0.10 and 0.20 dex.
The cyano radical (CN) is a key molecule across many different factions of astronomy and chemistry. Accurate, empirical rovibronic energy levels with uncertainties are determined for 8 doublet states of CN using the Marvel{} (Measured Active Rotational-Vibrational Energy Levels) algorithm. otrans{} transitions were validated from osources{} different published sources to generate oenergy{} spin-rovibronic energy levels. The empirical energy levels obtained from the Marvel{} analysis are compared to current energy levels from the Mollist{} line list. The Mollist{} transition frequencies are updated with Marvel{} energy level data which brings the frequencies obtained through experimental data up to alert{77.3%} from the original 11.3%, with 92.6% of the transitions with intensities over 10$^{-23}$ cm/molecule at 1000 K now known from experimental data. At 2000 K, 100.0% of the partition function is recovered using only Marvel{} energy levels, while 98.2% is still recovered at 5000 K.
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