Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userOccurrence of Mixed Phase in Bi0.5Sr0.5Mn0.9Cr0.1O3 bulk sample: Electron Paramagnetic Resonance and Magnetization Studies
82
0
0.0
(
0
)
Ask ChatGPT about the research
No Arabic abstract
We study the effects of 10% Cr substitution in Mn sites of Bi0.5Sr0.5MnO3 on the antiferromagnetic (AFM) (TN ~ 110 K) transition using structural, magnetic and electron paramagnetic resonance (EPR) techniques. Field cooled (FC) and zero field cooled (ZFC) magnetization measurements done from 400 K down to 4 K show that the compound is in the paramagnetic (PM) phase till 50 K where it undergoes a transition to a short range ferromagnetic phase (FM). Electron paramagnetic resonance measurements performed in the temperature range 300 K till 80 K conform with the magnetization measurements as symmetric signals are observed owing to the paramagnetic phase. Below 80 K, signals become asymmetric. Electron paramagnetic resonance intensity peaks at ~ 110 K, the decreasing intensity below this temperature confirming the presence of antiferromagnetism. We conclude that below 50 K the magnetization and EPR results are consistent with a cluster glass phase of BSMCO, where ferromagnetic clusters coexist with an antiferromagnetic background.
rate research
Read More
We study and compare magnetic and electron paramagnetic resonance behaviors of bulk and nanoparticles of Nd(1-x)CaxMnO3 in hole doped (x = 0.4;NCMOH) and electron doped (x = 0.6;NCMOE) samples. NCMOH in bulk form shows a complex temperature dependence of magnetization M(T), with a charge ordering (CO) transition at around 250 K, an antiferromagnetic (AFM) transition at around 150 K and a transition to a canted AFM phase/mixed phase at around 80 K. Bulk NCMOE behaves quite differently with just a charge ordering transition at around 280 K, thus providing a striking example of the so called electron-hole asymmetry. While our magnetization data on bulk samples are consistent with the earlier reports, the new results on the nanoparticles bring out drastic effects of size reduction. They show that M(T) behaviors of the two nano samples are essentially similar in addition to the absence of the charge order in them thus providing strong evidence for vanishing of the electron-hole asymmetry in nanomanganites. This conclusion is further corroborated by electron paramagnetic resonance studies which show that the large difference in the g-values and their temperature dependence found for the two bulk samples disappears as they approach a common behavior in the corresponding nano samples.
Nd_0.67Sr_0.33MnO_3 nanoparticles with the grain size of about 30 nm are prepared by sol-gel method.These nanopowders are annealed at four different temperatures viz. 800 oC, 900 oC, 1000 oC and 1100 oC to study the effect of particle size on magnetic, transport and electron magnetic resonance (EMR) spectral parameters. The samples are characterized by XRD, SEM, EDAX and TEM. The ac susceptibility experiments show that as the particle size increases the ferromagnetic to paramagnetic transition temperature (Tc) decreases. The metal-insulator transition temperature also changes with the particle size as revealed by resistivity measurements. EMR spectra of the nanopowders are recorded from room temperature down to 4K using an X-band EPR spectrometer. the spectra could be fitted using two broad-Gaussian lineshapes below Tc and suggested the ferromagnetic nature of the samples. Above Tc a single Lorenzian fits the signals as expetced for paramagnetic samples. The EMR spectral parameters are found to be different from the bulk (polycrystalline)sample data. The spectral parameters show variation with the particle size. The presence of the two signals in the ferromagnetic phase is attributed to core and shell regions in the nanoparticles. We could estimate the shell thickness from the EMR intensity data as 0.7 - 1 nm which agrees with other measurements.
Torque and magnetization measurements in magnetic fields $H$ up to 14 T were performed on CeCoIn$_5$ single crystals. The amplitude of the paramagnetic torque shows an $H^{2.3}$ dependence in the mixed state and an $H^{2}$ dependence in the normal state. In addition, the mixed-state magnetizations for both $Hparallel c$ and $Hparallel ab$ axes show anomalous behavior after the subtraction of the corresponding paramagnetic contributions as linear extrapolations of the normal-state magnetization. These experimental results point towards a nonlinear paramagnetic magnetization in the mixed state of CeCoIn$_5$, which is a result of the fact that both orbital and Pauli limiting effects dominate in the mixed state.
Magnetization and torque measurements were performed on CeCoIn$_5$ single crystals to study the mixed-state thermodynamics. These measurements allow the determination of both paramagnetic and vortex responses in the mixed-state magnetization. The paramagnetic magnetization is suppressed in the mixed state with the spin susceptibility increasing with increasing magnetic field. The dependence of spin susceptibility on magnetic field is due to the fact that heavy electrons contribute both to superconductivity and paramagnetism and a large Zeeman effect exists in this system. No anomaly in the vortex response was found within the investigated temperature and field range.
BaCuSi$_2$O$_6$, a $S=1/2$ quantum antiferromagnet with a double-layer structure of Cu$^{2+}$ ions in a distorted planar-rectangular coordination and with a dimerized spin singlet ground state, is studied by means of the electron paramagnetic resonance technique. It is argued that multiple absorptions observed at low temperatures are intimately related to a thermally-activated spin-triplet exciton superstructure. Analysis of the angular dependence of exciton modes in BaCuSi$_2$O$_6$ allows us to accurately estimate anisotropy parameters. In addition, the temperature dependence of EPR intensity and linewidth is discussed.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
