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Register a new userReconciliation of quantum local master equations with thermodynamics
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The study of open quantum systems often relies on approximate master equations derived under the assumptions of weak coupling to the environment. However when the system is made of several interacting subsystems such a derivation is in many cases very hard. An alternative method, employed especially in the modelling of transport in mesoscopic systems, consists in using {it local} master equations containing Lindblad operators acting locally only on the corresponding subsystem. It has been shown that this approach however generates inconsistencies with the laws of thermodynamics. In this paper we demonstrate that using a microscopic model of local master equations based on repeated collisions all thermodynamic inconsistencies can be resolved by correctly taking into account the breaking of global detailed balance related to the work cost of maintaining the collisions. We provide examples based on a chain of quantum harmonic oscillators whose ends are connected to thermal reservoirs at different temperatures. We prove that this system behaves precisely as a quantum heat engine or refrigerator, with properties that are fully consistent with basic thermodynamics.
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Local master equations are a widespread tool to model open quantum systems, especially in the context of many-body systems. These equations, however, are believed to lead to thermodynamic anomalies and violation of the laws of thermodynamics. In contrast, here we rigorously prove that local master equations are consistent with thermodynamics and its laws without resorting to a microscopic model, as done in previous works. In particular, we consider a quantum system in contact with multiple baths and identify the relevant contributions to the total energy, heat currents and entropy production rate. We show that the second law of thermodynamics holds when one considers the proper expression we derive for the heat currents. We confirm the results for the quantum heat currents by using a heuristic argument that connects the quantum probability currents with the energy currents, using an analogous approach as in classical stochastic thermodynamics. We finally use our results to investigate the thermodynamic properties of a set of quantum rotors operating as thermal devices and show that a suitable design of three rotors can work as an absorption refrigerator or a thermal rectifier. For the machines considered here, we also perform an optimisation of the system parameters using an algorithm of reinforcement learning.
We provide a rigorous construction of Markovian master equations for a wide class of quantum systems that encompass quadratic models of finite size, linearly coupled to an environment modeled by a set of independent thermal baths. Our theory can be applied for both fermionic and bosonic models in any number of physical dimensions, and does not require any particular spatial symmetry of the global system. We show that, for non-degenerate systems under a full secular approximation, the effective Lindblad operators are the normal modes of the system, with coupling constants that explicitly depend on the transformation matrices that diagonalize the Hamiltonian. Both the dynamics and the steady-state (guaranteed to be unique) properties can be obtained with a polynomial amount of resources in the system size. We also address the particle and energy current flowing through the system in a minimal two-bath scheme and find that they hold the structure of Landauers formula, being thermodynamically consistent.
Deep quantum neural networks may provide a promising way to achieve quantum learning advantage with noisy intermediate scale quantum devices. Here, we use deep quantum feedforward neural networks capable of universal quantum computation to represent the mixed states for open quantum many-body systems and introduce a variational method with quantum derivatives to solve the master equation for dynamics and stationary states. Owning to the special structure of the quantum networks, this approach enjoys a number of notable features, including the absence of barren plateaus, efficient quantum analogue of the backpropagation algorithm, resource-saving reuse of hidden qubits, general applicability independent of dimensionality and entanglement properties, as well as the convenient implementation of symmetries. As proof-of-principle demonstrations, we apply this approach to both one-dimensional transverse field Ising and two-dimensional $J_1-J_2$ models with dissipation, and show that it can efficiently capture their dynamics and stationary states with a desired accuracy.
We consider locally thermal states (for two qubits) with certain amount of quantum entanglement present between them. Unlike previous protocols we show how work can be extracted by performing local unitary operations on this state by allowing those two qubits to interact with thermal baths of different temperatures, thereby gradually removing the entanglement between them till they reach a direct product state. Also we demonstrate that, further work can be extracted from this direct product state by performing global unitary operation, thereby establishing that work can be extracted from a system composed of locally thermal subsystems even after removing quantum correlations between them if the subsystems are thermalized at different temperatures. Also we show that even if we consider a initial state where there is no entanglement between the two qubits, we can also extract work locally using our method.
Non-Markovian local in time master equations give a relatively simple way to describe the dynamics of open quantum systems with memory effects. Despite their simple form, there are still many misunderstandings related to the physical applicability and interpretation of these equations. Here we clarify these issues both in the case of quantum and classical master equations. We further introduce the concept of a classical non-Markov chain signified through negative jump rates in the chain configuration.
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