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Register a new userOptimal Orientations of Quartz Crystals for Bulk Acoustic Wave Resonators with the Consideration of Thermal Properties
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Piezoelectric crystals are widely used for acoustic wave resonators of different functioning modes and types including BAW and SAW. It is well-known that only some special orientations of crystals will exhibit desirable properties such as mode couplings, thermal sensitivity, acceleration sensitivity, and others that are important in design and applications of resonators. With extensive studies on physical properties in last decades and increasing industrial needs of novel products, it is necessary to comb the known knowledge of quartz crystal material for novel orientations and better products as agendas in the industry. With known material properties like elastic, piezoelectric, dielectric, and thermal constants, we can establish the relationships between vibrations and bias fields such as temperature to ensure a resonator immunizing from excessive response to changes causing significant degradation of resonator properties and performances. Since the theoretical framework of wave propagation in piezoelectric solids is known, we need to use the existing data and results for the validation of current orientations in actual products. The agreement will give us needed confidence of the theory and analytical procedures. Through rotations, we calculated physical properties as functions of angles and bias fields, enabling the calculation of resonator properties for the identification of optimal cuts. Such a procedure can also be applied to similar crystals for a careful examination of possible orientations to maximize the potential use of materials in acoustic wave resonators.
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We report the experimental realization of perfect sound absorption by sub-wavelength monopole and dipole resonators that exhibit degenerate resonant frequencies. This is achieved through the destructive interference of two resonators transmission responses, while the matching of their averaged impedances to that of air implies no backscattering, thereby leading to total absorption. Two examples, both using decorated membrane resonators (DMRs) as the basic units, are presented. The first is a flat panel comprising a DMR and a pair of coupled DMRs, while the second one is a ventilated short tube containing a DMR in conjunction with a sidewall DMR backed by a cavity. In both examples, near perfect absorption, up to 99.7%, has been observed with the airborne wavelength up to 1.2 m, which is at least an order of magnitude larger than the composite absorber. Excellent agreement between theory and experiment is obtained.
The magnetic and transport properties of Fe-deficient Fe5GeTe2 single crystals (Fe5-xGeTe2 with x~0.3) were studied and the impact of thermal processing was explored. Quenching crystals from the growth temperature has been previously shown to produce a metastable state that undergoes a strongly hysteretic first-order transition upon cooling below ~100K. The first-order transition impacts the magnetic properties, yielding an enhancement in the Curie temperature T_C from 270 to 310K. In the present work, T_HT ~550K has been identified as the temperature above which metastable crystals are obtained via quenching. Diffraction experiments reveal a structural change at this temperature, and significant stacking disorder occurs when samples are slowly cooled through this temperature range. The transport properties are demonstrated to be similar regardless of the crystals thermal history. The scattering of charge carriers appears to be dominated by moments fluctuating on the Fe(1) sublattice, which remain dynamic down to 100-120K. Maxima in the magnetoresistance and anomalous Hall resistance are observed near 120K. The Hall and Seebeck coefficients are also impacted by magnetic ordering on the Fe(1) sublattice. The data suggest that both electrons and holes contribute to conduction above 120K, but that electrons dominate at lower temperature when all of the Fe sublattices are magnetically ordered. This study demonstrates a strong coupling of the magnetism and transport properties in Fe5-xGeTe2 and complements the previous results that demonstrated strong magnetoelastic coupling as the Fe(1) moments order. The published version of this manuscript is DOI:10.1103/PhysRevMaterials.3.104401 (2019)
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