Do you want to publish a course? Click here

The anisotropy in the optical constants of quartz crystals for soft X-rays

137   0   0.0 ( 0 )
 Added by Anna Andrle
 Publication date 2020
  fields Physics
and research's language is English
 Authors A. Andrle




Ask ChatGPT about the research

The refractive index of a y-cut SiO$_2$ crystal surface is reconstructed from polarization dependent soft X-ray reflectometry measurements in the energy range from 45 eV to 620 eV. Due to the anisotropy of the crystal structure in the (100) and (001) directions, we observe a significant deviation of the measured reflectance at the Si-L$_{2,3}$ and O-K absorption edges. The anisotropy in the optical constants reconstructed from these data is also confirmed by ab initio Bethe-Salpeter Equation calculations of the O-K edge. This new experimental dataset expands the existing literature data for quartz optical constants significantly, particularly in the near-edge regions.



rate research

Read More

The equations for calculating diffraction profiles for bent crystals are revisited for both meridional and sagittal bending. Two approximated methods for computing diffraction profiles are treated: multilamellar and Penning-Polder. A common treatment of crystal anisotropy is included in these models. The formulation presented is implemented into the XOP package, completing and updating the crystal module that simulates diffraction profiles for perfect, mosaic and now distorted crystals by elastic bending.
76 - J. Wang , L. M. Zhang , S.Y. Wang 2017
Piezoelectric crystals are widely used for acoustic wave resonators of different functioning modes and types including BAW and SAW. It is well-known that only some special orientations of crystals will exhibit desirable properties such as mode couplings, thermal sensitivity, acceleration sensitivity, and others that are important in design and applications of resonators. With extensive studies on physical properties in last decades and increasing industrial needs of novel products, it is necessary to comb the known knowledge of quartz crystal material for novel orientations and better products as agendas in the industry. With known material properties like elastic, piezoelectric, dielectric, and thermal constants, we can establish the relationships between vibrations and bias fields such as temperature to ensure a resonator immunizing from excessive response to changes causing significant degradation of resonator properties and performances. Since the theoretical framework of wave propagation in piezoelectric solids is known, we need to use the existing data and results for the validation of current orientations in actual products. The agreement will give us needed confidence of the theory and analytical procedures. Through rotations, we calculated physical properties as functions of angles and bias fields, enabling the calculation of resonator properties for the identification of optimal cuts. Such a procedure can also be applied to similar crystals for a careful examination of possible orientations to maximize the potential use of materials in acoustic wave resonators.
It is known that the Zircon-type orthovanadates RVO4 show promise in many different applications as catalysts and optical materials. In this work, we demonstrate that the TbVO4 compound can be also used as magnetic refrigerant in efficient and ecofriendly cryocoolers due to its strong magnetocaloric effect at low temperature regime. The application of a relatively low magnetic field of 2 T along the easy magnetization axis (a) gives rise to a maximum entropy change of about 20 J/kg K at 4 K. More interestingly, under sufficiently high magnetic fields, the isothermal entropy change -{Delta}ST remains approximately constant over a wide temperature range which is highly appreciated from a practical point of view. In the magnetic field change of 7 T, -{Delta}ST that reaches roughly 22 J/kg K remains practically unchanged between 0 and 34 K leading to an outstanding refrigerant capacity of about 823 J/kg. On the other hand, the lowering of crystallographic symmetry from the tetragonal to the orthorhombic structure occurring close to 33 K as confirmed by Raman scattering data results in a strong magnetic anisotropy. Accordingly, strong thermal effects can be also obtained simply by spinning the TbVO4 single crystals between their hard and easy orientations in constant magnetic fields instead the standard magnetization-demagnetization process. Such rotating magnetocaloric effects would open the way for the implementation of TbVO4 in a new generation of compact and simplified magnetic refrigerators that can be dedicated to the liquefaction of hydrogen and helium.
We study the stability of various kinds of graphene samples under soft X-ray irradiation. Our results show that in single layer exfoliated graphene (a closer analogue to two dimensional material), the in-plane carbon-carbon bonds are unstable under X-ray irradiation, resulting in nanocrystalline structures. As the interaction along the third dimension increases by increasing the number of graphene layers or through the interaction with the substrate (epitaxial graphene), the effect of X-ray irradiation decreases and eventually becomes negligible for graphite and epitaxial graphene. Our results demonstrate the importance of the interaction along the third dimension in stabilizing the long range in-plane carbon-carbon bonding, and suggest the possibility of using X-ray to pattern graphene nanostructures in exfoliated graphene.
Piezoelectric quartz SiO2 crystals are widely used in industry as oscillators. As a natural mineral, quartz and its relevant silicates are also of interest of geoscience and mineralogy. However, the nucleation and growth of quartz crystals is difficult to control and not fully understood. Here we report successful solid state crystallization of thin film of amorphous GeO2 into quartz on various substrates including Al2O3, MgAl2O4, MgO, LaAlO3 and SrTiO3. At relatively low annealing temperatures, the crystallization process is spherulitic: with fibers growing radially from the nucleation centers and the crystal lattice rotating along the growth direction with a linear dependence between the rotation angle and the distance to the core. For increasingly higher annealing temperatures, quartz crystals begin to form. The edges of the sample play an important role facilitating nucleation followed by growth sweeping inward until the whole film is crystallized. Control of the growth allows single crystalline quartz to be synthesized. Our study reveals the complexity of the nucleation and growth process of quartz and provides insight for further studies.
comments
Fetching comments Fetching comments
mircosoft-partner

هل ترغب بارسال اشعارات عن اخر التحديثات في شمرا-اكاديميا