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Register a new userCarbon chemistry in IRC+10216: Infrared detection of diacetylene
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We present the detection of C4H2 for first time in the envelope of the C-rich AGB star IRC+10216 based on high spectral resolution mid-IR observations carried out with the Texas Echelon-cross-Echelle Spectrograph (TEXES) mounted on the Infrared Telescope Facility (IRTF). The obtained spectrum contains 24 narrow absorption features above the detection limit identified as lines of the ro-vibrational C4H2 band nu6+nu8(sigma_u^+). The analysis of these lines through a ro-vibrational diagram indicates that the column density of C4H2 is 2.4(1.5)E+16 cm^(-2). Diacetylene is distributed in two excitation populations accounting for 20 and 80% of the total column density and with rotational temperatures of 47(7) and 420(120) K, respectively. This two-folded rotational temperature suggests that the absorbing gas is located beyond ~0.4~20R* from the star with a noticeable cold contribution outwards from ~10~500R*. This outer shell matches up with the place where cyanoacetylenes and carbon chains are known to form due to the action of the Galactic dissociating radiation field on the neutral gas coming from the inner layers of the envelope.
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Linear carbon chains are common in various types of astronomical molecular sources. Possible formation mechanisms involve both bottom-up and top-down routes. We have carried out a combined observational and modeling study of the formation of carbon chains in the C-star envelope IRC+10216, where the polymerization of acetylene and hydrogen cyanide induced by ultraviolet photons can drive the formation of linear carbon chains of increasing length. We have used ALMA to map the emission of 3 mm rotational lines of the hydrocarbon radicals C2H, C4H, and C6H, and the CN-containing species CN, C3N, HC3N, and HC5N with an angular resolution of 1. The spatial distribution of all these species is a hollow, 5-10 wide, spherical shell located at a radius of 10-20 from the star, with no appreciable emission close to the star. Our observations resolve the broad shell of carbon chains into thinner sub-shells which are 1-2 wide and not fully concentric, indicating that the mass loss process has been discontinuous and not fully isotropic. The radial distributions of the species mapped reveal subtle differences: while the hydrocarbon radicals have very similar radial distributions, the CN-containing species show more diverse distributions, with HC3N appearing earlier in the expansion and the radical CN extending later than the rest of the species. The observed morphology can be rationalized by a chemical model in which the growth of polyynes is mainly produced by rapid gas-phase chemical reactions of C2H and C4H radicals with unsaturated hydrocarbons, while cyanopolyynes are mainly formed from polyynes in gas-phase reactions with CN and C3N radicals.
A single dish monitoring of millimeter maser lines SiS J=14-13 and HCN nu_2 = 1^f J=3-2 and several other rotational lines is reported for the archetypal carbon star IRC+10216. Relative line strength variations of 5%~30% are found for eight molecular line features with respect to selected reference lines. Definite line-shape variation is found in limited velocity intervals of the SiS and HCN line profiles. The asymmetrical line profiles of the two lines are mainly due to the varying components. Their dominant varying components of the line profiles have similar periods and phases as the IR light variation, although both quantities show some degree of velocity dependence; there is also variability asymmetry between the blue and red line wings of both lines. Combining the velocities and amplitudes with a wind velocity model, we suggest that the line profile variations are due to SiS and HCN masing lines emanating from the wind acceleration zone. The possible link of the variabilities to thermal, dynamical and/or chemical processes within or under this region is also discussed.
Aims. We model the chemistry of the inner wind of the carbon star IRC+10216 and consider the effect of periodic shocks induced by the stellar pulsation on the gas to follow the non-equilibrium chemistry in the shocked gas layers. We consider a very complete set of chemical families, including hydrocarbons and aromatics, hydrides, halogens and phosphorous-bearing species. Derived abundances are compared to the latest observational data from large surveys and Herschel. Results. The shocks induce a non-equilibrium chemistry in the dust formation zone of IRC+10216 where the collision destruction of CO in the post-shock gas triggers the formation of O-bearing species (H2O, SiO). Most of the modelled abundances agree very well with the latest values derived from Herschel data on IRC+10216. Hydrides form a family of abundant species that are expelled into the intermediate envelope. In particular, HF traps all the atomic fluorine in the dust formation zone. Halogens are also abundant and their chemistry is independent of the C/O ratio of the star. Therefore, HCl and other Cl-bearing species should also be present in the inner wind of O-rich AGB or supergiant stars. We identify a specific region ranging from 2.5 R* to 4 R*, where polycyclic aromatic hydrocarbons form and grow. The estimated carbon dust-to-gas mass ratio derived from the mass of aromatics ranges from 1.2 x 10^(-3) to 5.8 x 10^{-3} and agrees well with existing observational values. The aromatic formation region is located outside hot layers where SiC2 is produced as a bi-product of silicon carbide dust synthesis. Finally, we predict that some molecular lines will show flux variation with pulsation phase and time (e.g., H2O) while other species will not (e.g., CO). These variations merely reflect the non-equilibrium chemistry that destroys and reforms molecules over a pulsation period in the shocked gas of the dust formation zone.
New high-resolution far-infrared (FIR) observations of both ortho- and para-NH3 transitions toward IRC+10216 were obtained with Herschel, with the goal of determining the ammonia abundance and constraining the distribution of NH3 in the envelope of IRC+10216. We used the Heterodyne Instrument for the Far Infrared (HIFI) on board Herschel to observe all rotational transitions up to the J=3 level (three ortho- and six para-NH3 lines). We conducted non-LTE multilevel radiative transfer modelling, including the effects of near-infrared (NIR) radiative pumping through vibrational transitions. We found that NIR pumping is of key importance for understanding the excitation of rotational levels of NH3. The derived NH3 abundances relative to molecular hydrogen were (2.8+-0.5)x10^{-8} for ortho-NH3 and (3.2^{+0.7}_{-0.6})x10^{-8} for para-NH3, consistent with an ortho/para ratio of 1. These values are in a rough agreement with abundances derived from the inversion transitions, as well as with the total abundance of NH3 inferred from the MIR absorption lines. To explain the observed rotational transitions, ammonia must be formed near to the central star at a radius close to the end of the wind acceleration region, but no larger than about 20 stellar radii (1 sigma confidence level).
The J,K = 1,0-0,0 rotational transition of phosphine (PH3) at 267 GHz has been tentatively identified with a T_MB = 40 mK spectral line observed with the IRAM 30-m telescope in the C-star envelope IRC+10216. A radiative transfer model has been used to fit the observed line profile. The derived PH3 abundance relative to H2 is 6 x 10^(-9), although it may have a large uncertainty due to the lack of knowledge about the spatial distribution of this species. If our identification is correct, it implies that PH3 has a similar abundance to that reported for HCP in this source, and that these two molecules (HCP and PH3) together take up about 5 % of phosphorus in IRC+10216. The abundance of PH3, as that of other hydrides in this source, is not well explained by conventional gas phase LTE and non-LTE chemical models, and may imply formation on grain surfaces.
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