No Arabic abstract
The microwave clock frequency of the $|5s~^2S_{1/2}, F=0,m_F=0 rangle leftrightarrow |5s~^2S_{1/2}, F=1,m_F=0 rangle$ transition in the $^{113}$Cd$^+$ ion has been reported as 15199862855.0192(10) Hz [Opt. Lett. {bf 40}, 4249 (2015)]. Fractional systematic due to the black-body radiation (BBR) shift ($beta$) arising from the Stark effect in the above clock transition was used as $-1.1 times 10^{-16}$ from our unpublished preliminary estimation. We present here a precise value as $beta=-1.815(77) times 10^{-16}$ by carrying out rigorous calculations of third-order polarizabilities of the hyperfine levels associated with the clock transition. This is determined by evaluating matrix elements of the magnetic dipole hyperfine interaction Hamiltonian, electric dipole operator and energies between many low-lying states of $^{113}$Cd$^+$. We employ all-order relativistic many-body theories in the frameworks of Fock-space coupled-cluster and relativistic multi-configuration Dirac-Fock methods.
We report sympathetic cooling of $^{113}$Cd$^+$ by laser-cooled $^{40}$Ca$^+$ in a linear Paul trap for microwave clocks. Long-term low-temperature confinement of $^{113}$Cd$^+$ ions was achieved. The temperature of these ions was measured at $90(10)$ mK, and the corresponding uncertainty arising from the second-order Doppler shifts was estimated to a level of $2times10^{-17}$. Up to $4.2times10^5$ Cd$^+$ ions were confined in the trap, and the confinement time constant was measured to be 84 hours. After three hours of confinement, there were still $10^5$ Cd$^+$ ions present, indicating that this Ca$^+$--Cd$^+$ dual ion system is surprisingly stable. The ac Stark shift was induced by the Ca$^+$ lasers and fluorescence, which was carefully estimated to an accuracy of $5.4(0.5)times10^{-17}$ using a high-accuracy textit{ab initio} approach. The Dick-effect-limited Allan deviation was also deduced because deadtimes were shorter. These results indicate that a microwave clock based on this sympathetic cooling scheme holds promise in providing ultra-high frequency accuracy and stability.
We measure the dynamic differential scalar polarizabilities at 10.6 $mu$m for two candidate clock transitions in $^{176}mathrm{Lu}^+$. The fractional black body radiation (BBR) shifts at 300 K for the $^1S_0 leftrightarrow {^3D_1}$ and $^1S_0 leftrightarrow {^3D_2}$ transitions are evaluated to be $-1.36,(9) times 10^{-18}$ and $2.70 ,(21) times10^{-17}$, respectively. The former is the lowest of any established optical atomic clock.
Collisions with background gas can perturb the transition frequency of trapped ions in an optical atomic clock. We develop a non-perturbative framework based on a quantum channel description of the scattering process, and use it to derive a master equation which leads to a simple analytic expression for the collisional frequency shift. As a demonstration of our method, we calculate the frequency shift of the Sr$^+$ optical atomic clock transition due to elastic collisions with helium.
With the uncertainty of the optical clocks improving to the order of 10-18, the probe light used to detect the clock transition has demonstrated nonnegligible Stark shift, provoking to precisely evaluate this shift. Here, we demonstrate a frequency modulation technique to realize a large measurement lever arm of the probe Stark shift with no cost of the measurement accuracy of the interleaved stabilization method. This frequency-modulated spectrum is theoretical described and experimental verified. The probe Stark shift coefficient of the 87Sr optical lattice clock is experimentally determined as -(45.97+/-3.51) Hz/(W/cm2) using this frequency modulation spectroscopy.
We investigate roles of electron correlation effects in the determination of $g_j$ factors of the $ns~^2S_{1/2}$ ($n$=5,6,7), $np~^2P_{1/2,3/2}$ ($n$=5,6), $5d~^2D_{3/2,5/2}$, and $4f~^2F_{5/2,7/2}$ states of the singly ionized cadmium (Cd$^+$) ion. Single and double excited configurations along with important valence triple excited configurations through relativistic coupled-cluster (RCC) theory are taken into account for incorporating electron correlation effects in our calculations. We find significant contributions from the triples to the lower $S$ and $P$ states for attaining high accuracy results. The contributions of Breit interaction and lower-order quantum electrodynamics effects, such as vacuum polarization and self-energy corrections, are also estimated using the RCC theory and are quoted explicitly. In addition, we present energies of the aforementioned states from our calculations and compare them with the experimental results to validate $g_j$ values. Using the $g_j$ factor of the ground state, systematical shift due to the Zeeman effect in the microwave clock frequency of the $|5s~^2S_{1/2}, F=0,m_F=0 rangle leftrightarrow |5s~^2S_{1/2}, F=1,m_F=0 rangle$ transition in $^{113}$Cd$^+$ ion has been estimated.