No Arabic abstract
Recent angle-resolved spectroscopy in BiS$_2$-based superconductors has indicated that the superconducting gap amplitude possesses remarkable anisotropy and/or a sign change on a small Fermi pocket around $X$ point. It implies a possibility of an unconventional pairing state. Here we study the gap anisotropy in superconductivity mediated by inherent charge/quadrupole fluctuations in an extended Hubbard model, which includes inter-site interaction between Bi and S atoms. The first-principles downfolded band structure is composed of Bi $6p_x/p_y$ and S $3p_x/p_y$ orbitals on a BiS$_2$ single layer. Evaluating the linearized gap equation, we find that the ferroic charge/quadrupole fluctuation driven by the inter-site interaction leads to a fully-gapped $d_{x^2-y^2}$-wave pairing state, in which the gap amplitude has sizable anisotropy on the Fermi surface.
We implement the Bogoliubov-de Gennes (BdG) equation in a screened Korringa-Kohn-Rostoker (KKR) method for solving, self-consistently, the superconducting state for 3d crystals. This method combines the full complexity of the underlying electronic structure and Fermi surface geometry with a simple phenomenological parametrisation for the superconductivity. We apply this theoretical framework to the known s-wave superconductors Nb, Pb, and MgB$_2$. In these materials multiple distinct peaks at the gap in the density of states were observed, showing significant gap anisotropy which is in good agreement with experiment. Qualitatively, the results can be explained in terms of the k-dependent Fermi velocities on the Fermi surface sheets exploiting concepts from BCS theory.
Striped phases in which spin and charge separate into different regions in the material have been proposed to account for the unusual properties of the high-$T_c$ cuprate superconductors. The driving force for a striped phase is the charge distribution, which self-organizes itself into linear regions. In the highest $T_c$ materials such regions are not static but fluctuate in time. Neutrons, having no charge, can not directly observe these fluctuations but they can be observed indirectly by their effect on the phonons. Neutron scattering measurements have been made using a specialized technique to study the phonon line shapes in four crystals with oxygen doping levels varying from highly underdoped to optimal doping. It is shown that fluctuating charge stripes exist over the whole doping range, and become visible below temperatures somewhat higher than the pseudogap temperature.
We develop the realistic minimal electronic model for recently discovered BiS$_2$ superconductors including the spin-orbit coupling based on a first-principles band structure calculations. Due to strong spin-orbit coupling, characteristic for the Bi-based systems, the tight-binding low-energy model necessarily includes $p_x$, $p_y$, and $p_z$ orbitals. We analyze a potential Cooper-pairing instability from purely repulsive interaction for the moderate electronic correlations using the so-called leading angular harmonics approximation (LAHA). For small and intermediate doping concentrations we find the dominant instabilities to be $d_{x^2-y^2}$-wave, and $s_{pm}$-wave symmetries, respectively. At the same time, in the absence of the sizable spin fluctuations the intra and interband Coulomb repulsion are of the same strength, which yields the strongly anisotropic behaviour of the superconducting gaps on the Fermi surface in agreement with recent ARPES findings. In addition, we find that the Fermi surface topology for BiS$_2$ layered systems at large electron doping can resembles the doped iron-based pnictide superconductors with electron and hole Fermi surfaces with sufficient nesting between them. This could provide further boost to increase $T_c$ in these systems.
We report Raman scattering measurement of charge nematic fluctuations in the tetragonal phase of BaFe$_2$As$_2$ and Sr(Fe$_{1-x}$Co$_x$)$_2$As$_2$ (x=0.04) single crystals. In both systems, the observed nematic fluctuations are found to exhibit divergent Curie-Weiss like behavior with very similar characteristic temperature scales, indicating a universal tendency towards charge nematic order in 122 iron-based superconductors.
We report a systematic investigation on c-axis point-contact Andreev reflection (PCAR) in BaFe$_{2-x}$Ni$_x$As$_2$ superconducting single crystals from underdoped to overdoped regions (0.075 $leq xleq 0.15$). At optimal doping ($x=0.1$) the PCAR spectrum feature the structures of two superconducting gap and electron-boson coupling mode. In the $spm$ scenario, quantitative analysis using a generalized Blonder-Tinkham-Klapwijk (BTK) formalism with two gaps: one isotropic and another angle dependent, suggest a nodeless state in strong-coupling limit with gap minima on the Fermi surfaces. Upon crossing above the optimal doping ($x > 0.1$), the PCAR spectrum show an in-gap sharp narrow peak at low bias, in contrast to the case of underdoped samples ($x < 0.1$), signaling the onset of deepened gap minima or nodes in the superconducting gap. This result provides evidence of the modulation of the gap amplitude with doping concentration, consistent with the calculations for the orbital dependent pair interaction mediated by the antiferromagnetic spin fluctuations.