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Defect in the Joint Spectrum of Hydrogen due to Monodromy

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 Added by Holger Waalkens
 Publication date 2016
  fields Physics
and research's language is English




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In addition to the well known case of spherical coordinates the hydrogen atom separates in three further coordinate systems. Separating in a particular coordinate system defines a system of three commuting operators. We show that the joint spectrum of the Hamilton operator, and the $z$-components of the angular momentum and quantum Laplace-Runge-Lenz vectors obtained from separation in prolate spheroidal coordinates has quantum monodromy for energies sufficiently close to the ionization threshold. This means that one cannot globally assign quantum numbers to the joint spectrum. Whereas the principal quantum number $n$ and the magnetic quantum number $m$ correspond to the Bohr-Sommerfeld quantization of globally defined classical actions a third quantum number cannot be globally defined because the third action is globally multi valued.



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The notion of monodromy was introduced by J. J. Duistermaat as the first obstruction to the existence of global action coordinates in integrable Hamiltonian systems. This invariant was extensively studied since then and was shown to be non-trivial in various concrete examples of finite-dimensional integrable systems. The goal of the present paper is to give a brief overview of monodromy and discuss some of its generalisations. In particular, we will discuss the monodromy around a focus-focus singularity and the notions of quantum, fractional and scattering monodromy. The exposition will be complemented with a number of examples and open problems.
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