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Register a new userHeavy ion irradiation of crystalline water ice
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Under cosmic irradiation, the interstellar water ice mantles evolve towards a compact amorphous state. Crystalline ice amorphisation was previously monitored mainly in the keV to hundreds of keV ion energies. We experimentally investigate heavy ion irradiation amorphisation of crystalline ice, at high energies closer to true cosmic rays, and explore the water-ice sputtering yield. We irradiated thin crystalline ice films with MeV to GeV swift ion beams, produced at the GANIL accelerator. The ice infrared spectral evolution as a function of fluence is monitored with in-situ infrared spectroscopy (induced amorphisation of the initial crystalline state into a compact amorphous phase). The crystalline ice amorphisation cross-section is measured in the high electronic stopping-power range for different temperatures. At large fluence, the ice sputtering is measured on the infrared spectra, and the fitted sputtering-yield dependence, combined with previous measurements, is quadratic over three decades of electronic stopping power. The final state of cosmic ray irradiation for porous amorphous and crystalline ice, as monitored by infrared spectroscopy, is the same, but with a large difference in cross-section, hence in time scale in an astrophysical context. The cosmic ray water-ice sputtering rates compete with the UV photodesorption yields reported in the literature. The prevalence of direct cosmic ray sputtering over cosmic-ray induced photons photodesorption may be particularly true for ices strongly bonded to the ice mantles surfaces, such as hydrogen-bonded ice structures or more generally the so-called polar ices.
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The main goal of this work is to compare the effects induced in ices of astrophysical relevance by high-energy ions, simulating cosmic rays, and by vacuum ultraviolet (UV) photons. This comparison relies on in situ infrared spectroscopy of irradiated CH3OH:NH3 ice. Swift heavy ions were provided by the GANIL accelerator. The source of UV was a microwave-stimulated hydrogen flow discharge lamp. The deposited energy doses were similar for ion beams and UV photons to allow a direct comparison. A variety of organic species was detected during irradiation and later during ice warm-up. These products are common to ion and UV irradiation for doses up to a few tens of eV per molecule. Only the relative abundance of the CO product, after ice irradiation, was clearly higher in the ion irradiation experiments. For some ice mixture compositions, the irradiation products formed depend only weakly on the type of irradiation, swift heavy ions, or UV photons. This simplifies the chemical modeling of energetic ice processing in space.
Water ice has a strong spectral feature at a wavelength of approximately $3~mu$m, which plays a vital role in our understanding of the icy universe. In this study, we investigate the scattering polarization of this water-ice feature. The linear polarization degree of light scattered by $mu$m-sized icy grains is known to be enhanced at the ice band; however, the dependence of this polarization enhancement on various grain properties is unclear. We find that the enhanced polarization at the ice band is sensitive to the presence of $mu$m-sized grains as well as their ice abundance. We demonstrate that this enhancement is caused by the high absorbency of the water-ice feature, which attenuates internal scattering and renders the surface reflection dominant over internal scattering. Additionally, we compare our models with polarimetric observations of the low-mass protostar L1551 IRS 5. Our results show that scattering by a maximum grain radius of a few microns with a low water-ice abundance is consistent with observations. Thus, scattering polarization of the water-ice feature is a useful tool for characterizing ice properties in various astronomical environments.
In the denser and colder ($leq$20 K) regions of the interstellar medium (ISM), near-infrared observations have revealed the presence of sub-micron sized dust grains covered by several layers of Htextsubscript{2}O-dominated ices and dirtied by the presence of other volatile species. Whether a molecule is in the gas or solid-phase depends on its binding energy (BE) on ice surfaces. Thus, BEs are crucial parameters for the astrochemical models that aim to reproduce the observed evolution of the ISM chemistry. In general, BEs can be inferred either from experimental techniques or by theoretical computations. In this work, we present a reliable computational methodology to evaluate the BEs of a large set (21) of astrochemical relevant species. We considered different periodic surface models of both crystalline and amorphous nature to mimic the interstellar water ice mantles. Both models ensure that hydrogen bond cooperativity is fully taken into account at variance with the small ice cluster models. Density functional theory adopting both B3LYP-D3 and M06-2X functionals was used to predict the species/ice structure and their BE. As expected from the complexity of the ice surfaces, we found that each molecule can experience multiple BE values, which depend on its structure and position at the ice surface. A comparison of our computed data with literature data shows agreement in some cases and (large) differences in others. We discuss some astrophysical implications that show the importance of calculating BEs using more realistic interstellar ice surfaces to have reliable values for inclusion in the astrochemical models.
The optical properties of ice in the far infrared are important for models of protoplanetary and debris disks. In this report we derive a new set of data for the absorption (represented by the imaginary part of the refractive index $kappa$) of crystalline water ice in this spectral range, including a detailed inspection of the temperature dependence, which had not been done in such detail before. We measured the transmission of three ice layers with different thicknesses at temperatures $vartheta = 10...250$K and present data at wavelengths $lambda=80...625$ microns. We found a change in the spectral dependence of $kappa$ at a wavelength of $175 pm 6$ microns. At shorter wavelengths, $kappa$ exhibits a constant flat slope and no significant temperature dependence. Long-ward of that wavelength, the slope gets steeper and has a clear, approximately linear temperature dependence. This change in the behaviour is probably caused by a characteristic absorption band of water ice. The measured data were fitted by a power-law model that analytically describes the absorption behaviour at an arbitrary temperature. This model can readily be applied to any object of interest, for instance a protoplanetary or a debris disk. To illustrate how the model works, we simulated the spectral energy distribution (SED) of the resolved, large debris disk around the nearby solar-type star HD 207129. Replacing our ice model by another, commonly used data set for water ice results in a different SED slope at longer wavelengths. This leads to changes in the characteristic model parameters of the disk, such as the inferred particle size distribution, and affects the interpretation of the underlying collisional physics of the disk.
The single crystal of tris(thiourea)zinc sulphate (Zn[CS(NH2)2]3SO4) was irradiated by 150 MeV Au9+ swift heavy ions and analyzed in comparison with pure crystal for crystalline perfection and optical properties. The Fourier transform infrared and x-ray powder diffraction inferred that swift ions lead the disordering and breaking of molecular bonds in lattice without formation of new structural phases. High resolution X-ray diffraction (HRXRD) revealed the abundance of point defects, and formation of mosaics and low angle grain boundaries in the irradiated region of crystal. The swift ion irradiation found to affect the lattice vibrational modes and functional groups significantly. The defects induced by heavy ions act as the color centers and resulted in enhance of photoluminescence emission intensity. The optical transparency and band gap found to be decreased.
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