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Register a new userInvestigating the Minimum Energy Principle in Searches for New Molecular Species - the Case of H$_{2}$C$_{3}$O Isomers
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Recently, Lattelais et al. (2009) have interpreted aggregated observations of molecular isomers to suggest that there exists a minimum energy principle, such that molecular formation will favor more stable molecular isomers for thermodynamic reasons. To test the predictive power of this principle, we have fully characterized the spectra of the three isomers of C$_{3}$H$_{2}$O toward the well known molecular region Sgr B2(N). Evidence for the detection of the isomers cyclopropenone (c-C$_{3}$H$_{2}$O) and propynal (HCCCHO) is presented, along with evidence for the non-detection of the lowest zero-point energy isomer, propadienone (CH$_2$CCO). We interpret these observations as evidence that chemical formation pathways, which may be under kinetic control, have a more pronounced effect on final isomer abundances than thermodynamic effects such as the minimum energy principle.
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Complex organic molecules (COMs) have been detected in a variety of interstellar sources. The abundances of these COMs in warming sources can be explained by syntheses linked to increasing temperatures and densities, allowing quasi-thermal chemical reactions to occur rapidly enough to produce observable amounts of COMs, both in the gas phase, and upon dust grain ice mantles. The COMs produced on grains then become gaseous as the temperature increases sufficiently to allow their thermal desorption. The recent observation of gaseous COMs in cold sources has not been fully explained by these gas-phase and dust grain production routes. Radiolysis chemistry is a possible non-thermal method of producing COMs in cold dark clouds. This new method greatly increases the modeled abundance of selected COMs upon the ice surface and within the ice mantle due to excitation and ionization events from cosmic ray bombardment. We examine the effect of radiolysis on three C$_{2}$H$_{4}$O$_{2}$ isomers -- methyl formate (HCOOCH$_3$), glycolaldehyde (HCOCH$_2$OH), and acetic acid (CH$_3$COOH) -- and a chemically similar molecule, dimethyl ether (CH$_3$OCH$_3$), in cold dark clouds. We then compare our modelled gaseous abundances with observed abundances in TMC-1, L1689B, and B1-b.
Understanding the degree of chemical complexity that can be reached in star-forming regions, together with the identification of precursors of the building blocks of life in the interstellar medium, is one of the goals of astrochemistry. Unbiased spectral surveys with large bandwidth and high spectral resolution are thus needed, to resolve line blending in chemically rich sources and identify complex organic molecules. This kind of observations has been successfully carried out, mainly towards the Galactic Center, a region that shows peculiar environmental conditions. We present an unbiased spectral survey at 3mm of one of the most chemically rich hot molecular cores located outside the Galactic Center, in the high-mass star-forming region G31.41+0.31. In this first paper, we present the survey and discuss the detection of the 3 isomers of C$_{2}$H$_{4}$O$_{2}$: methyl formate, glycolaldehyde and acetic acid. Observations were carried out with ALMA and cover the entire Band 3 from 84 to 116 GHz with an angular resolution of $1.2^{}$x$1.2^{}$ and a spectral resolution of $sim0.488$ MHz. The transitions of the 3 molecules have been analyzed with the software XCLASS. All three isomers were detected and methyl formate and acetic acid abundances in G31 are the highest detected up to now, if compared to sources in literature. The size of the emission varies among the three isomers with acetic acid showing the most compact emission while methyl formate the most extended. The comparison with chemical models suggests the necessity of grain-surface routes for the formation of methyl formate in G31, while for glycolaldehyde both scenarios could be feasible. Proposed grain-surface reaction for acetic acid is not able to reproduce the observed abundance in this work, while gas-phase scenario should be further tested due to large uncertainties.
We use integral field spectroscopic (IFS) observations from Gemini North Multi-Object Spectrograph (GMOS-N) of a group of four H II regions and the surrounding gas in the central region of the blue compact dwarf (BCD) galaxy NGC 4670. At spatial scales of $sim$ 9 pc, we map the spatial distribution of a variety of physical properties of the ionised gas: internal dust attenuation, kinematics, stellar age, star-formation rate, emission line ratios and chemical abundances. The region of study is found to be photoionised. Using the robust direct T$_e$-method, we estimate metallicity, nitrogen-to-oxygen ratio and helium abundance of the four H II regions. The same parameters are also mapped for the entire region using the HII-CHI-mistry code. We find that log(N/O) is increased in the region where the Wolf-Rayet bump is detected.The region coincides with the continuum region, around which we detect a slight increase in He abundance. We estimate the number of WC4, WN2-4 and WN7-9 stars from the integrated spectrum of WR bump region. We study the relation between log(N/O) and 12 + log(O/H) using the spatially-resolved data of the FOV as well as the integrated data of the H II regions from ten BCDs. We find an unexpected negative trend between N/O and metallicity. Several scenarios are explored to explain this trend, including nitrogen enrichment, and variations in star formation efficiency via chemical evolution models.
Fragmentation branching ratios of electronically excited molecular species are of first importance for the modeling of gas phase interstellar chemistry. Despite experimental and theoretical efforts that have been done during the last two decades there is still a strong lack of detailed information on those quantities for many molecules such as Cn, CnH or C3H2. Our aim is to provide astrochemical databases with more realistic branching ratios for Cn (n=2 to 10), CnH (n=2 to 4), and C3H2 molecules that are electronically excited either by dissociative recombination, photodissociation, or cosmic ray processes, when no detailed calculations or measurements exist in literature. High velocity collision in an inverse kinematics scheme was used to measure the complete fragmentation pattern of electronically excited Cn (n=2 to 10), CnH (n=2 to 4), and C3H2 molecules. Branching ratios of dissociation where deduced from those experiments. The full set of branching ratios was used as a new input in chemical models and branching ratio modification effects observed in astrochemical networks that describe the dense cold Taurus Molecular Cloud-1 and the photon dominated Horse Head region. The comparison between the branching ratios obtained in this work and other types of experiments showed a good agreement. It was interpreted as the signature of a statistical behavior of the fragmentation. The branching ratios we obtained lead to an increase of the C3 production together with a larger dispersion of the daughter fragments. The introduction of these new values in the photon dominated region model of the Horse Head nebula increases the abundance of C3 and C3H, but reduces the abundances of the larger Cn and hydrocarbons at a visual extinction Av smaller than 4.
The compositions of nascent planets depend on the compositions of their birth disks. In particular, the elemental compositions of Gas Giant gaseous envelopes depend on the elemental composition of the disk gas from which the envelope is accreted. Previous models demonstrated that sequential freeze-out of O and C-bearing volatiles in disks will result in an supersolar C/O ratios and subsolar C/H ratios in the gas between water and CO snowlines. This result does not take into account, however, the expected grain growth and radial drift of pebbles in disks, and the accompanying re-distribution of volatiles from the outer to the inner disk. Using a toy model we demonstrate that when drift is considered, CO is enhanced between the water and CO snowline, resulting in both supersolar C/O and C/H ratios in the disk gas in the Gas Giant formation zone. This result appears robust to the details of the disk model as long as there is substantial pebble drift across the CO snowline, and the efficiency of CO vapor diffusion is limited. Gas Giants that accrete their gaseous envelopes exterior to the water snowline and do not experience substantial core-envelope mixing, may thus present both superstellar C/O and C/H ratios in their atmospheres. Pebble drift will also affect the nitrogen and noble gas abundances in the planet forming zones, which may explain some of Jupiters peculiar abundance patterns.
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