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Register a new userThe GUAPOS project: G31.41+0.31 Unbiased ALMA sPectral Observational Survey -- I. Isomers of C$_{2}$H$_{4}$O$_{2}$
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Understanding the degree of chemical complexity that can be reached in star-forming regions, together with the identification of precursors of the building blocks of life in the interstellar medium, is one of the goals of astrochemistry. Unbiased spectral surveys with large bandwidth and high spectral resolution are thus needed, to resolve line blending in chemically rich sources and identify complex organic molecules. This kind of observations has been successfully carried out, mainly towards the Galactic Center, a region that shows peculiar environmental conditions. We present an unbiased spectral survey at 3mm of one of the most chemically rich hot molecular cores located outside the Galactic Center, in the high-mass star-forming region G31.41+0.31. In this first paper, we present the survey and discuss the detection of the 3 isomers of C$_{2}$H$_{4}$O$_{2}$: methyl formate, glycolaldehyde and acetic acid. Observations were carried out with ALMA and cover the entire Band 3 from 84 to 116 GHz with an angular resolution of $1.2^{}$x$1.2^{}$ and a spectral resolution of $sim0.488$ MHz. The transitions of the 3 molecules have been analyzed with the software XCLASS. All three isomers were detected and methyl formate and acetic acid abundances in G31 are the highest detected up to now, if compared to sources in literature. The size of the emission varies among the three isomers with acetic acid showing the most compact emission while methyl formate the most extended. The comparison with chemical models suggests the necessity of grain-surface routes for the formation of methyl formate in G31, while for glycolaldehyde both scenarios could be feasible. Proposed grain-surface reaction for acetic acid is not able to reproduce the observed abundance in this work, while gas-phase scenario should be further tested due to large uncertainties.
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Complex organic molecules (COMs) have been detected in a variety of interstellar sources. The abundances of these COMs in warming sources can be explained by syntheses linked to increasing temperatures and densities, allowing quasi-thermal chemical reactions to occur rapidly enough to produce observable amounts of COMs, both in the gas phase, and upon dust grain ice mantles. The COMs produced on grains then become gaseous as the temperature increases sufficiently to allow their thermal desorption. The recent observation of gaseous COMs in cold sources has not been fully explained by these gas-phase and dust grain production routes. Radiolysis chemistry is a possible non-thermal method of producing COMs in cold dark clouds. This new method greatly increases the modeled abundance of selected COMs upon the ice surface and within the ice mantle due to excitation and ionization events from cosmic ray bombardment. We examine the effect of radiolysis on three C$_{2}$H$_{4}$O$_{2}$ isomers -- methyl formate (HCOOCH$_3$), glycolaldehyde (HCOCH$_2$OH), and acetic acid (CH$_3$COOH) -- and a chemically similar molecule, dimethyl ether (CH$_3$OCH$_3$), in cold dark clouds. We then compare our modelled gaseous abundances with observed abundances in TMC-1, L1689B, and B1-b.
Context. Submillimeter Array (SMA) 870 micron polarization observations of the hot molecular core G31.41+0.31 revealed one of the clearest examples up to date of an hourglass-shaped magnetic field morphology in a high-mass star-forming region. Aims. To better establish the role that the magnetic field plays in the collapse of G31.41+0.31, we carried out Atacama Large Millimeter/submillimeter Array (ALMA) observations of the polarized dust continuum emission at 1.3 mm with an angular resolution four times higher than that of the previous (sub)millimeter observations to achieve an unprecedented image of the magnetic field morphology. Methods. We used ALMA to perform full polarization observations at 233 GHz (Band 6). The resulting synthesized beam is 0.28x020 which, at the distance of the source, corresponds to a spatial resolution of ~875 au. Results. The observations resolve the structure of the magnetic field in G31.41+0.31 and allow us to study the field in detail. The polarized emission in the Main core of G31.41+0.41is successfully fit with a semi-analytical magnetostatic model of a toroid supported by magnetic fields. The best fit model suggests that the magnetic field is well represented by a poloidal field with a possible contribution of a toroidal component of ~10% of the poloidal component, oriented southeast to northwest at ~ -44 deg and with an inclination of ~-45 degr. The magnetic field is oriented perpendicular to the northeast to southwest velocity gradient detected in this core on scales from 1E3-1E4 au. This supports the hypothesis that the velocity gradient is due to rotation and suggests that such a rotation has little effect on the magnetic field. The strength of the magnetic field estimated in the central region of the core with the Davis-Chandrasekhar-Fermi method is ~8-13 mG and implies that the mass-to-flux ratio in this region is slightly supercritical ...
As part of our effort to search for circumstellar disks around high-mass stellar objects, we observed the well-known core G31.41+0.31 with ALMA at 1.4 mm with an angular resolution of~0.22 (~1700 au). The dust continuum emission has been resolved into two cores namely Main and NE. The Main core, which has the stronger emission and is the more chemically rich, has a diameter of ~5300 au, and is associated with two free-free continuum sources. The Main core looks featureless and homogeneous in dust continuum emission and does not present any hint of fragmentation. Each transition of CH3CN and CH3OCHO, both ground and vibrationally excited, as well as those of CH3CN isotopologues, shows a clear velocity gradient along the NE-SW direction, with velocity linearly increasing with distance from the center, consistent with solid-body rotation. However, when comparing the velocity field of transitions with different upper level energies, the rotation velocity increases with increasing energy of the transition, which suggests that the rotation speeds up towards the center. Spectral lines towards the dust continuum peak show an inverse P-Cygni profile that supports the existence of infall in the core. The infall velocity increases with the energy of the transition suggesting that the infall is accelerating towards the center of the core, consistent with gravitational collapse. Despite the monolithic appearance of the Main core, the presence of red-shifted absorption, the existence of two embedded free-free sources at the center, and the rotational spin-up are consistent with an unstable core undergoing fragmentation with infall and differential rotation due to conservation of angular momentum. Therefore, the most likely explanation for the monolithic morphology is that the large opacity of the dust emission prevents the detection of any inhomogeneity in the core.
Recently, Lattelais et al. (2009) have interpreted aggregated observations of molecular isomers to suggest that there exists a minimum energy principle, such that molecular formation will favor more stable molecular isomers for thermodynamic reasons. To test the predictive power of this principle, we have fully characterized the spectra of the three isomers of C$_{3}$H$_{2}$O toward the well known molecular region Sgr B2(N). Evidence for the detection of the isomers cyclopropenone (c-C$_{3}$H$_{2}$O) and propynal (HCCCHO) is presented, along with evidence for the non-detection of the lowest zero-point energy isomer, propadienone (CH$_2$CCO). We interpret these observations as evidence that chemical formation pathways, which may be under kinetic control, have a more pronounced effect on final isomer abundances than thermodynamic effects such as the minimum energy principle.
Using ALMA observations of the C$^{18}$O(2-1) line emission of the gas envelope of protostar L1527, we have reconstructed its morphology and kinematics under the assumption of axisymmetry about the west-east axis. The main original contribution to our understanding of the formation process of L1527 is the presentation of a simple 3D parameterisation based solely on regions that are not dominated by absorption. In the explored range ($sim$0.7 to 5 arcsec from the star) the model reproduces observations better than earlier attempts. The main results include: a measurement of the rotation velocity that confirms its evolution to Keplerian toward short distances; a measurement of the mean in-fall velocity, 0.43$pm$0.10 kms$^{-1}$, lower than free fall velocity, with no evidence for the significant $r$-dependence suggested by an earlier analysis; a measurement of the central mass, 0.23$pm$0.06 M$_{odot}$ within a distance of 1.5 arcsec from the star, in agreement with earlier estimates obtained from a different range of distances; evidence for a strong disc plane depression of the in-falling flux resulting in an $X$ shaped flow possibly caused by the freeze-out of CO molecules on dust grains; a measurement of the accretion rate, 3.5$pm$1.0 10$^{-7}$ M$_{odot}$yr$^{-1}$ at a distance of 1 arcsec (140 au) from the star; evidence for a 10$^circ$ tilt of the symmetry plane of the envelope about the line of sight, cancelling below $sim$3 arcsec from the star, but matching infrared observations and being also apparent on the sky map of the mean Doppler velocity.
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