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Register a new userConstitutive Relation for Nonlinear Response and Universality of Efficiency at Maximum Power for Tight-Coupling Heat Engines
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We present a unified perspective on nonequilibrium heat engines by generalizing nonlinear irreversible thermodynamics. For tight-coupling heat engines, a generic constitutive relation of nonlinear response accurate up to the quadratic order is derived from the symmetry argument and the stall condition. By applying this generic nonlinear constitutive relation to finite-time thermodynamics, we obtain the necessary and sufficient condition for the universality of efficiency at maximum power, which states that a tight-coupling heat engine takes the universal efficiency at maximum power up to the quadratic order if and only if either the engine symmetrically interacts with two heat reservoirs or the elementary thermal energy flowing through the engine matches the characteristic energy of the engine. As a result, we solve the following paradox: On the one hand, the universal quadratic term in the efficiency at maximum power for tight-coupling heat engines proved as a consequence of symmetry [M. Esposito, K. Lindenberg, and C. Van den Broeck, Phys. Rev. Lett. 102, 130602 (2009); S. Q. Sheng and Z. C. Tu, Phys. Rev. E 89, 012129 (2014)]; On the other hand, two typical heat engines including the Curzon-Ahlborn endoreversible heat engine [F. L. Curzon and B. Ahlborn, Am. J. Phys. 43, 22 (1975)] and the Feynman ratchet [Z. C. Tu, J. Phys. A 41, 312003 (2008)] recover the universal efficiency at maximum power regardless of any symmetry.
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Typical heat engines exhibit a kind of homotypy: The heat exchanges between a cyclic heat engine and its two heat reservoirs abide by the same function type; the forward and backward flows of an autonomous heat engine also conform to the same function type. This homotypy mathematically reflects in the existence of hidden symmetries for heat engines. The heat exchanges between the cyclic heat engine and its two reservoirs are dual under the joint transformation of parity inversion and time-reversal operation. Similarly, the forward and backward flows in the autonomous heat engine are also dual under the parity inversion. With the consideration of these hidden symmetries, we derive a generic nonlinear constitutive relation up to the quadratic order for tight-coupling cyclic heat engines and that for tight-coupling autonomous heat engines, respectively.
A unified $chi$-criterion for heat devices (including heat engines and refrigerators) which is defined as the product of the energy conversion efficiency and the heat absorbed per unit time by the working substance [de Tom{a}s emph{et al} 2012 textit{Phys. Rev. E} textbf{85} 010104(R)] is optimized for tight-coupling heat engines and refrigerators operating between two heat baths at temperatures $T_c$ and $T_h(>T_c)$. By taking a new convention on the thermodynamic flux related to the heat transfer between two baths, we find that for a refrigerator tightly and symmetrically coupled with two heat baths, the coefficient of performance (i.e., the energy conversion efficiency of refrigerators) at maximum $chi$ asymptotically approaches to $sqrt{varepsilon_C}$ when the relative temperature difference between two heat baths $varepsilon_C^{-1}equiv (T_h-T_c)/T_c$ is sufficiently small. Correspondingly, the efficiency at maximum $chi$ (equivalent to maximum power) for a heat engine tightly and symmetrically coupled with two heat baths is proved to be $eta_C/2+eta_C^2/8$ up to the second order term of $eta_Cequiv (T_h-T_c)/T_h$, which reverts to the universal efficiency at maximum power for tight-coupling heat engines operating between two heat baths at small temperature difference in the presence of left-right symmetry [Esposito emph{et al} 2009 textit{Phys. Rev. Lett.} textbf{102} 130602].
We study a class of cyclic Brownian heat engines in the framework of finite-time thermodynamics. For infinitely long cycle times, the engine works at the Carnot efficiency limit producing, however, zero power. For the efficiency at maximum power, we find a universal expression, different from the endoreversible Curzon-Ahlborn efficiency. Our results are illustrated with a simple one-dimensional engine working in and with a time-dependent harmonic potential.
We study the efficiency at maximum power, $eta^*$, of engines performing finite-time Carnot cycles between a hot and a cold reservoir at temperatures $T_h$ and $T_c$, respectively. For engines reaching Carnot efficiency $eta_C=1-T_c/T_h$ in the reversible limit (long cycle time, zero dissipation), we find in the limit of low dissipation that $eta^*$ is bounded from above by $eta_C/(2-eta_C)$ and from below by $eta_C/2$. These bounds are reached when the ratio of the dissipation during the cold and hot isothermal phases tend respectively to zero or infinity. For symmetric dissipation (ratio one) the Curzon-Ahlborn efficiency $eta_{CA}=1-sqrt{T_c/T_h}$ is recovered.
We introduce a simple two-level heat engine to study the efficiency in the condition of the maximum power output, depending on the energy levels from which the net work is extracted. In contrast to the quasi-statically operated Carnot engine whose efficiency reaches the theoretical maximum, recent research on more realistic engines operated in finite time has revealed other classes of efficiency such as the Curzon-Ahlborn efficiency maximizing the power output. We investigate yet another side with our heat engine model, which consists of pure relaxation and net work extraction processes from the population difference caused by different transition rates. Due to the nature of our model, the time-dependent part is completely decoupled from the other terms in the generated work. We derive analytically the optimal condition for transition rates maximizing the generated power output and discuss its implication on general premise of realistic heat engines. In particular, the optimal engine efficiency of our model is different from the Curzon-Ahlborn efficiency, although they share the universal linear and quadratic coefficients at the near-equilibrium limit. We further confirm our results by taking an alternative approach in terms of the entropy production at hot and cold reservoirs.
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