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Entropy production and information fluctuations along quantum trajectories

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 Added by Bruno Leggio
 Publication date 2013
  fields Physics
and research's language is English




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Employing the stochastic wave function method, we study quantum features of stochastic entropy production in nonequilibrium processes of open systems. It is demonstarted that continuous measurements on the environment introduce an additional, non-thermal contribution to the entropy flux, which is shown to be a direct consequence of quantum fluctuations. These features lead to a quantum definition of single trajectory entropy contributions, which accounts for the difference between classical and quantum trajectories and results in a quantum correction to the standard form of the integral fluctuation theorem.

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In thermodynamics, entropy production and work quantify irreversibility and the consumption of useful energy, respectively, when a system is driven out of equilibrium. For quantum systems, these quantities can be identified at the stochastic level by unravelling the systems evolution in terms of quantum jump trajectories. We here derive a general formula for computing the joint statistics of work and entropy production in Markovian driven quantum systems, whose instantaneous steady-states are of Gibbs form. If the driven system remains close to the instantaneous Gibbs state at all times, we show that the corresponding two-variable cumulant generating function implies a joint detailed fluctuation theorem so long as detailed balance is satisfied. As a corollary, we derive a modified fluctuation-dissipation relation (FDR) for the entropy production alone, applicable to transitions between arbitrary steady-states, and for systems that violate detailed balance. This FDR contains a term arising from genuinely quantum fluctuations, and extends an analogous relation from classical thermodynamics to the quantum regime.
We employ a quantum trajectory approach to characterize synchronization and phase-locking between open quantum systems in nonequilibrium steady states. We exemplify our proposal for the paradigmatic case of two quantum Van der Pol oscillators interacting through dissipative coupling. We show the deep impact of synchronization on the statistics of phase-locking indicators and other correlation measures defined for single trajectories, spotting a link between the presence of synchronization and the emergence of large tails in the probability distribution for the entanglement along trajectories. Our results shed new light on fundamental issues regarding quantum synchronization providing new methods for its precise quantification.
We develop a martingale theory to describe fluctuations of entropy production for open quantum systems in nonequilbrium steady states. Using the formalism of quantum jump trajectories, we identify a decomposition of entropy production into an exponential martingale and a purely quantum term, both obeying integral fluctuation theorems. An important consequence of this approach is the derivation of a set of genuine universal results for stopping-time and infimum statistics of stochastic entropy production. Finally we complement the general formalism with numerical simulations of a qubit system.
The entropy production in dissipative processes is the essence of the arrow of time and the second law of thermodynamics. For dissipation of quantum systems, it was recently shown that the entropy production contains indeed two contributions: a classical one and a quantum one. Here we show that for degenerate (or near-degenerate) quantum systems there are additional quantum contributions which, remarkably, can become negative. Furthermore, such negative contributions are related to significant changes in the ongoing thermodynamics. This includes phenomena such as generation of coherences between degenerate energy levels (called horizontal coherences), alteration of energy exchanges and, last but not least, reversal of the natural convergence of the populations toward the thermal equilibrium state. Going further, we establish a complementarity relation between horizontal coherences and population convergence, particularly enlightening for understanding heat flow reversals. Conservation laws of the different types of coherences are derived. Some consequences for thermal machines and resource theory of coherence are suggested.
The quench dynamics of many-body quantum systems may exhibit non-analyticities in the Loschmidt echo, a phenomenon known as dynamical phase transition (DPT). Despite considerable research into the underlying mechanisms behind this phenomenon, several open questions still remain. Motivated by this, we put forth a detailed study of DPTs from the perspective of quantum phase space and entropy production, a key concept in thermodynamics. We focus on the Lipkin-Meshkov-Glick model and use spin coherent states to construct the corresponding Husimi-$Q$ quasi-probability distribution. The entropy of the $Q$-function, known as Wehrl entropy, provides a measure of the coarse-grained dynamics of the system and, therefore, evolves non-trivially even for closed systems. We show that critical quenches lead to a quasi-monotonic growth of the Wehrl entropy in time, combined with small oscillations. The former reflects the information scrambling characteristic of these transitions and serves as a measure of entropy production. On the other hand, the small oscillations imply negative entropy production rates and, therefore, signal the recurrences of the Loschmidt echo. Finally, we also study a Gaussification of the model based on a modified Holstein-Primakoff approximation. This allows us to identify the relative contribution of the low energy sector to the emergence of DPTs. The results presented in this article are relevant not only from the dynamical quantum phase transition perspective, but also for the field of quantum thermodynamics, since they point out that the Wehrl entropy can be used as a viable measure of entropy production.
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