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Register a new userThe Second Law of Thermodynamics under Unitary Evolution and External Operations
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A microscopic definition of the thermodynamic entropy in an isolated quantum system must satisfy (i) additivity, (ii) extensivity and (iii) the second law of thermodynamics. We show that the diagonal entropy, which is the Shannon entropy in the energy eigenbasis at each instant of time, meets the first two requirements and that the third requirement is satisfied if an arbitrary external operation is performed at typical times. In terms of the diagonal entropy, thermodynamic irreversibility follows from the facts that the Hamiltonian dynamics restricts quantum trajectories under unitary evolution and that the external operation is performed without referring to any particular information about the microscopic state of the system.
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We derive a generalization of the Second Law of Thermodynamics that uses Bayesian updates to explicitly incorporate the effects of a measurement of a system at some point in its evolution. By allowing an experimenters knowledge to be updated by the measurement process, this formulation resolves a tension between the fact that the entropy of a statistical system can sometimes fluctuate downward and the information-theoretic idea that knowledge of a stochastically-evolving system degrades over time. The Bayesian Second Law can be written as $Delta H(rho_m, rho) + langle mathcal{Q}rangle_{F|m}geq 0$, where $Delta H(rho_m, rho)$ is the change in the cross entropy between the original phase-space probability distribution $rho$ and the measurement-updated distribution $rho_m$, and $langle mathcal{Q}rangle_{F|m}$ is the expectation value of a generalized heat flow out of the system. We also derive refin
It is shown that the laws of thermodynamics are extremely robust under generalizations of the form of entropy. Using the Bregman-type relative entropy, the Clausius inequality is proved to be always valid. This implies that thermodynamics is highly universal and does not rule out consistent generalization of the maximum entropy method.
The second law of classical thermodynamics, based on the positivity of the entropy production, only holds for deterministic processes. Therefore the Second Law in stochastic quantum thermodynamics may not hold. By making a fundamental connection between thermodynamics and information theory we will introduce a new way of defining the Second Law which holds for both deterministic classical and stochastic quantum thermodynamics. Our work incorporates information well into the Second Law and also provides a thermodynamic operational meaning for negative and positive entropy production.
Recent experiments began to explore the topological properties of quench dynamics, i.e. the time evolution following a sudden change in the Hamiltonian, via tomography of quantum gases in optical lattices. In contrast to the well established theory for static band insulators or periodically driven systems, at present it is not clear whether, and how, topological invariants can be defined for a general quench of band insulators. Previous work solved a special case of this problem beautifully using Hopf mapping of two-band Hamiltonians in two dimensions. But it only works for topologically trivial initial state and is hard to generalize to multiband systems or other dimensions. Here we introduce the concept of loop unitary constructed from the unitary time-evolution operator, and show its homotopy invariant fully characterizes the dynamical topology. For two-band systems in two dimensions, we prove that the invariant is precisely equal to the change in the Chern number across the quench regardless of the initial state. We further show that the nontrivial dynamical topology manifests as hedgehog defects in the loop unitary, and also as winding and linking of its eigenvectors along a curve where dynamical quantum phase transition occurs. This opens up a systematic route to classify and characterize quantum quench dynamics.
The nature of the behaviour of an isolated many-body quantum system periodically driven in time has been an open question since the beginning of quantum mechanics. After an initial transient, such a system is known to synchronize with the driving; in contrast to the non-driven case, no fundamental principle has been proposed for constructing the resulting non-equilibrium state. Here, we analytically show that, for a class of integrable systems, the relevant ensemble is constructed by maximizing an appropriately defined entropy subject to constraints, which we explicitly identify. This result constitutes a generalisation of the concepts of equilibrium statistical mechanics to a class of far-from-equilibrium-systems, up to now mainly accessible using ad-hoc methods.
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