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Non-Equilibrium Chemistry of Dynamically Evolving Prestellar Cores: I. Basic Magnetic and Non-Magnetic Models and Parameter Studies

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 Added by Konstantinos Tassis
 Publication date 2011
  fields Physics
and research's language is English




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We combine dynamical and non-equilibrium chemical modeling of evolving prestellar molecular cloud cores, and explore the evolution of molecular abundances in the contracting core. We model both magnetic cores, with varying degrees of initial magnetic support, and non-magnetic cores, with varying collapse delay times. We explore, through a parameter study, the competing effects of various model parameters in the evolving molecular abundances, including the elemental C/O ratio, the temperature, and the cosmic-ray ionization rate. We find that different models show their largest quantitative differences at the center of the core, whereas the outer layers, which evolve slower, have abundances which are severely degenerate among different dynamical models. There is a large range of possible abundance values for different models at a fixed evolutionary stage (central density), which demonstrates the large potential of chemical differentiation in prestellar cores. However, degeneracies among different models, compounded with uncertainties induced by other model parameters, make it difficult to discriminate among dynamical models. To address these difficulties, we identify abundance ratios between particular molecules, the measurement of which would have maximal potential for discrimination among the different models examined here. In particular, we find that the ratios between NH3 and CO; NH2 and CO; NH3 and HCO+ are sensitive to the evolutionary timescale, and that the ratio between HCN and OH is sensitive to the C/O ratio. Finally, we demonstrate that measurements of the central deviation (central depletion or enhancement) of abundances of certain molecules are good indicators of the dynamics of the core.



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We study the effect that non-equilibrium chemistry in dynamical models of collapsing molecular cloud cores has on measurements of the magnetic field in these cores, the degree of ionization, and the mean molecular weight of ions. We find that OH and CN, usually used in Zeeman observations of the line-of-sight magnetic field, have an abundance that decreases toward the center of the core much faster than the density increases. As a result, Zeeman observations tend to sample the outer layers of the core and consistently underestimate the core magnetic field. The degree of ionization follows a complicated dependence on the number density at central densities up to 10^5 cm^{-3} for magnetic models and 10^6 cm^{-3} in non-magnetic models. At higher central densities the scaling approaches a power-law with a slope of -0.6 and a normalization which depends on the cosmic-ray ionization rate {zeta} and the temperature T as ({zeta}T)^1/2. The mean molecular weight of ions is systematically lower than the usually assumed value of 20 - 30, and, at high densities, approaches a value of 3 due to the asymptotic dominance of the H3+ ion. This significantly lower value implies that ambipolar diffusion operates faster.
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We present numerical simulations of the evolution of a supernova (SN) remnant expanding into a uniform background medium with density $n_H = 1.0$ cm$^{-3}$ and temperature of $10^4$ K. We include a dynamically evolving non-equilibrium ionisation (NEI) network (consisting of all the ions of H, He, C, N, O, Ne, Mg, Si, S, Fe), frequency dependent radiation transfer (RT), thermal conduction, and a simple dust evolution model, all intra-coupled to each other and to the hydrodynamics. We assume spherical symmetry. Photo-ionisation, radiation losses, photo-heating, charge-exchange heating/cooling and radiation pressure are calculated on-the-fly depending on the local radiation field and ion fractions. We find that the dynamics and energetics (but not the emission spectra) of the SN remnants can be well modelled by collisional equilibrium cooling curves even in the absence of non-equilibrium cooling and radiative transport. We find that the effect of precursor ionising radiation at different stages of SN remnant are dominated by rapid cooling of the shock and differ from steady state shocks. The predicted column densities of different ions such as N II, C IV and N V, can be higher by up to several orders of magnitude compared to steady state shocks. We also present some high esolution emission spectra that can be compared with the observed remnants to obtain important information about the physical and chemical states of the remnant, as well as constrain the background ISM.
Time and history dependent magnetization has been observed in a wide variety of materials, which are collectively termed as the glassy magnetic systems. However, such systems showing similar non-equilibrium magnetic response can be microscopically very different and they can be distinguished by carefully looking into the details of the observed metastable magnetic behavior. Canonical spin glass is the most well studied member of this class and has been extensively investigated both experimentally and theoretically over the last five decades. In canonical spin glasses, the low temperature magnetic state obtained by cooling across the spin glass transition temperature in presence of an applied magnetic field is known as the field cooled (FC) state. This FC state in canonical spin glass is widely believed as an equilibrium state arising out of a thermodynamic second order phase transition. Here, we show that the FC state in canonical spin glass is not really an equilibrium state of the system. We report careful dc magnetization and ac susceptibility measurements on two canonical spin glass systems, AuMn (1.8%) and AgMn (1.1%). The dc magnetization in the FC state shows clear temperature dependence. In addition, the magnetization shows a distinct thermal hysteresis in the temperature regime below the spin glass transition temperature. On the other hand, the temperature dependence of ac susceptibility has clear frequency dispersion below spin glass transition in the FC state prepared by cooling the sample in the presence of a dc-bias field. We further distinguish the metastable response of the FC state of canonical spin glass from the metastable response the FC state in an entirely different class of glassy magnetic system namely magnetic glass, where the non-equilibrium behavior is associated with the kinetic-arrest of a first order magnetic phase transition.
131 - Konstantinos Tassis , 2012
Comparison of linewidths of spectral line profiles of ions and neutral molecules have been recently used to estimate the strength of the magnetic field in turbulent star-forming regions. However, the ion (HCO+) and neutral (HCN) species used in such studies may not be necessarily co-evolving at every scale and density and may thus not trace the same regions. Here, we use coupled chemical/dynamical models of evolving prestellar molecular cloud cores including non-equilibrium chemistry, with and without magnetic fields, to study the spatial distribution of HCO+ and HCN, which have been used in observations of spectral linewidth differences to date. In addition, we seek new ion-neutral pairs that are good candidates for such observations because they have similar evolution and are approximately co-spatial in our models. We identify three such good candidate pairs: HCO+/NO, HCO+/CO, and NO+/NO.
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