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Register a new userQuantum Thermodynamic Cycles and Quantum Heat Engines (II)
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Authors
H. T. Quan
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We study the quantum mechanical generalization of force or pressure, and then we extend the classical thermodynamic isobaric process to quantum mechanical systems. Based on these efforts, we are able to study the quantum version of thermodynamic cycles that consist of quantum isobaric process, such as quantum Brayton cycle and quantum Diesel cycle. We also consider the implementation of quantum Brayton cycle and quantum Diesel cycle with some model systems, such as single particle in 1D box and single-mode radiation field in a cavity. These studies lay the microscopic (quantum mechanical) foundation for Szilard-Zurek single molecule engine.
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Recently, Zhang {em et al.} [PRA, {bf 75}, 062102 (2007)] extended Kieus interesting work on the quantum Otto engine [PRL, {bf 93}, 140403 (2004)] by considering as working substance a bipartite quantum system $AB$ composed of subsystems $A$ and $B$. In this paper, we express the net work done $W_{AB}$ by such an engine explicitly in terms of the macroscopic bath temperatures and information theoretic quantities associated with the microscopic quantum states of the working substance. This allows us to gain insights into the dependence of positive $W_{AB}$ on the quantum properties of the states. We illustrate with a two-qubit XY chain as the working substance. Inspired by the expression, we propose a plausible formula for the work derivable from the subsystems. We show that there is a critical entanglement beyond which it is impossible to draw positive work locally from the individual subsystems while $W_{AB}$ is positive. This could be another interesting manifestation of quantum nonlocality.
Given a quantum heat engine that operates in a cycle that reaches maximal efficiency for a time-dependent Hamiltonian H(t) of the working substance, with overall controllable driving H(t) = g(t) H, we study the deviation of the efficiency from the optimal value due to a generic time-independent perturbation in the Hamiltonian. We show that for a working substance consisting of two two-level systems, by suitably tuning the interaction, the deviation can be suppressed up to the third order in the perturbation parameter-and thus almost retaining the optimality of the engine.
Owing to the ubiquity of synchronization in the classical world, it is interesting to study its behavior in quantum systems. Though quantum synchronisation has been investigated in many systems, a clear connection to quantum technology applications is lacking. We bridge this gap and show that nanoscale heat engines are a natural platform to study quantum synchronization and always possess a stable limit cycle. Furthermore, we demonstrate an intimate relationship between the power of a heat engine and its phase-locking properties by proving that synchronization places an upper bound on the achievable steady-state power of the engine. Finally, we show that the efficiency of the engine sets a point in terms of the bath temperatures where synchronization vanishes. We link the physical phenomenon of synchronization with the emerging field of quantum thermodynamics by establishing quantum synchronization as a mechanism of stable phase coherence.
We study the physical mechanism of Maxwells Demon (MD) helping to do extra work in thermodynamic cycles, by describing measurement of position, insertion of wall and information erasing of MD in a quantum mechanical fashion. The heat engine is exemplified with one molecule confined in an infinitely deep square potential inserted with a movable solid wall, while the MD is modeled as a two-level system (TLS) for measuring and controlling the motion of the molecule. It is discovered that the the MD with quantum coherence or on a lower temperature than that of the heat bath of the particle would enhance the ability of the whole work substance formed by the system plus the MD to do work outside. This observation reveals that the role of the MD essentially is to drive the whole work substance being off equilibrium, or equivalently working with an effective temperature difference. The elaborate studies with this model explicitly reveal the effect of finite size off the classical limit or thermodynamic limit, which contradicts the common sense on Szilard heat engine (SHE). The quantum SHEs efficiency is evaluated in detail to prove the validity of second law of thermodynamics.
The efficiency of small thermal machines is typically a fluctuating quantity. We here study the efficiency large deviation function of two exemplary quantum heat engines, the harmonic oscillator and the two-level Otto cycles. While the efficiency statistics follows the universal theory of Verley et al. [Nature Commun. 5, 4721 (2014)] for nonadiabatic driving, we find that the latter framework does not apply in the adiabatic regime. We relate this unusual property to the perfect anticorrelation between work output and heat input that generically occurs in the broad class of scale-invariant adiabatic quantum Otto heat engines and suppresses thermal as well as quantum fluctuations.
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