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Register a new userImpact of nonideal cycles on the efficiency of quantum heat engines
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Given a quantum heat engine that operates in a cycle that reaches maximal efficiency for a time-dependent Hamiltonian H(t) of the working substance, with overall controllable driving H(t) = g(t) H, we study the deviation of the efficiency from the optimal value due to a generic time-independent perturbation in the Hamiltonian. We show that for a working substance consisting of two two-level systems, by suitably tuning the interaction, the deviation can be suppressed up to the third order in the perturbation parameter-and thus almost retaining the optimality of the engine.
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The efficiency of small thermal machines is typically a fluctuating quantity. We here study the efficiency large deviation function of two exemplary quantum heat engines, the harmonic oscillator and the two-level Otto cycles. While the efficiency statistics follows the universal theory of Verley et al. [Nature Commun. 5, 4721 (2014)] for nonadiabatic driving, we find that the latter framework does not apply in the adiabatic regime. We relate this unusual property to the perfect anticorrelation between work output and heat input that generically occurs in the broad class of scale-invariant adiabatic quantum Otto heat engines and suppresses thermal as well as quantum fluctuations.
Recent predictions for quantum-mechanical enhancements in the operation of small heat engines have raised renewed interest in their study from both a fundamental perspective and in view of applications. One essential question is whether collective effects may help to carry enhancements over larger scales, when increasing the number of systems composing the working substance of the engine. Such enhancements may consider not only power and efficiency, that is its performance, but, additionally, its constancy, i.e. the stability of the engine with respect to unavoidable environmental fluctuations. We explore this issue by introducing a many-body quantum heat engine model composed by spin pairs working in continuous operation. We study how power, efficiency and constancy scale with the number of spins composing the engine, and obtain analytical expressions in the macroscopic limit. Our results predict power enhancements, both in finite-size and macroscopic cases, for a broad range of system parameters and temperatures, without compromising the engine efficiency, as well as coherence-enhanced constancy for large but finite sizes. We also discuss these quantities in connection to Thermodynamic Uncertainty Relations (TUR).
We study the quantum mechanical generalization of force or pressure, and then we extend the classical thermodynamic isobaric process to quantum mechanical systems. Based on these efforts, we are able to study the quantum version of thermodynamic cycles that consist of quantum isobaric process, such as quantum Brayton cycle and quantum Diesel cycle. We also consider the implementation of quantum Brayton cycle and quantum Diesel cycle with some model systems, such as single particle in 1D box and single-mode radiation field in a cavity. These studies lay the microscopic (quantum mechanical) foundation for Szilard-Zurek single molecule engine.
The efficiency at maximum power has been investigated extensively, yet the practical control scheme to achieve it remains elusive. We fill such gap with a stepwise Carnot-like cycle, which consists the discrete isothermal process (DIP) and adiabatic process. With DIP, we validate the widely adopted assumption of mathscr{C}/t relation of the irreversible entropy generation S^{(mathrm{ir})}, and show the explicit dependence of the coefficient mathscr{C} on the fluctuation of the speed of tuning energy levels as well as the microscopic coupling constants to the heat baths. Such dependence allows to control the irreversible entropy generation by choosing specific control schemes. We further demonstrate the achievable efficiency at maximum power and the corresponding control scheme with the simple two-level system. Our current work opens new avenues for the experimental test, which was not feasible due to the lack the of the practical control scheme in the previous low-dissipation model or its equivalents.
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