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Dynamics of Annihilation II: Fluctuations of Global Quantities

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 Added by Pablo Maynar
 Publication date 2008
  fields Physics
and research's language is English




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We develop a theory for fluctuations and correlations in a gas evolving under ballistic annihilation dynamics. Starting from the hierarchy of equations governing the evolution of microscopic densities in phase space, we subsequently restrict to a regime of spatial homogeneity, and obtain explicit predictions for the fluctuations and time correlation of the total number of particles, total linear momentum and total kinetic energy. Cross-correlations between these quantities are worked out as well. These predictions are successfully tested against Molecular Dynamics and Monte-Carlo simulations. This provides strong support for the theoretical approach developed, including the hydrodynamic treatment of the spectrum of the linearized Boltzmann operator. This article is a companion paper to arXiv:0801.2299 and makes use of the spectral analysis reported there.



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We study the non-equilibrium statistical mechanics of a system of freely moving particles, in which binary encounters lead either to an elastic collision or to the disappearance of the pair. Such a system of {em ballistic annihilation} therefore constantly looses particles. The dynamics of perturbations around the free decay regime is investigated from the spectral properties of the linearized Boltzmann operator, that characterize linear excitations on all time scales. The linearized Boltzmann equation is solved in the hydrodynamic limit by a projection technique, which yields the evolution equations for the relevant coarse-grained fields and expressions for the transport coefficients. We finally present the results of Molecular Dynamics simulations that validate the theoretical predictions.
We study the fluctuations of the Gaussian model, with conservation of the order parameter, evolving in contact with a thermal bath quenched from inverse temperature $beta _i$ to a final one $beta _f$. At every time there exists a critical value $s_c(t)$ of the variance $s$ of the order parameter per degree of freedom such that the fluctuations with $s>s_c(t)$ are characterized by a macroscopic contribution of the zero wavevector mode, similarly to what occurs in an ordinary condensation transition. We show that the probability of fluctuations with $s<inf_t [s_c(t)]$, for which condensation never occurs, rapidly converges towards a stationary behavior. By contrast, the process of populating the zero wavevector mode of the variance, which takes place for $s>inf _t [s_c(t)]$, induces a slow non-equilibrium dynamics resembling that of systems quenched across a phase transition.
We study the dynamics of the fluctuations of the variance $s$ of the order parameter of the Gaussian model, following a temperature quench of the thermal bath. At each time $t$, there is a critical value $s_c(t)$ of $s$ such that fluctuations with $s>s_c(t)$ are realized by condensed configurations of the systems, i.e., a single degree of freedom contributes macroscopically to $s$. This phenomenon, which is closely related to the usual condensation occurring on average quantities, is usually referred to as {it condensation of fluctuations}. We show that the probability of fluctuations with $s<inf_t [s_c(t)]$, associated to configurations that never condense, after the quench converges rapidly and in an adiabatic way towards the new equilibrium value. The probability of fluctuations with $s>inf_t [s_c(t)]$, instead, displays a slow and more complex behavior, because the macroscopic population of the condensing degree of freedom is involved.
We consider the dynamics of fluctuations in the quantum asymmetric simple exclusion process (Q-ASEP) with periodic boundary conditions. The Q-ASEP describes a chain of spinless fermions with random hoppings that are induced by a Markovian environment. We show that fluctuations of the fermionic degrees of freedom obey evolution equations of Lindblad type, and derive the corresponding Lindbladians. We identify the underlying algebraic structure by mapping them to non-Hermitian spin chains and demonstrate that the operator space fragments into exponentially many (in system size) sectors that are invariant under time evolution. At the level of quadratic fluctuations we consider the Lindbladian on the sectors that determine the late time dynamics for the particular case of the quantum symmetric simple exclusion process (Q-SSEP). We show that the corresponding blocks in some cases correspond to known Yang-Baxter integrable models and investigate the level-spacing statistics in others. We carry out a detailed analysis of the steady states and slow modes that govern the late time behaviour and show that the dynamics of fluctuations of observables is described in terms of closed sets of coupled linear differential-difference equations. The behaviour of the solutions to these equations is essentially diffusive but with relevant deviations, that at sufficiently late times and large distances can be described in terms of a continuum scaling limit which we construct. We numerically check the validity of this scaling limit over a significant range of time and space scales. These results are then applied to the study of operator spreading at large scales, focusing on out-of-time ordered correlators and operator entanglement.
255 - Arti Dua , R. Adhikari 2008
Recent experiments using fluorescence spectroscopy have been able to probe the dynamics of conformational fluctuations in proteins. The fluctuations are Gaussian but do not decay exponentially, and are therefore, non-Markovian. We present a theory where non-Markovian fluctuation dynamics emerges naturally from the superposition of the Markovian fluctuations of the normal modes of the protein. A Rouse-like dynamics of the normal modes provides very good agreement to the experimentally measured correlation functions. We provide simple scaling arguments rationalising our results.
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