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Register a new userDynamics of fluctuations in the Gaussian model with dissipative Langevin Dynamics
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We study the dynamics of the fluctuations of the variance $s$ of the order parameter of the Gaussian model, following a temperature quench of the thermal bath. At each time $t$, there is a critical value $s_c(t)$ of $s$ such that fluctuations with $s>s_c(t)$ are realized by condensed configurations of the systems, i.e., a single degree of freedom contributes macroscopically to $s$. This phenomenon, which is closely related to the usual condensation occurring on average quantities, is usually referred to as {it condensation of fluctuations}. We show that the probability of fluctuations with $s<inf_t [s_c(t)]$, associated to configurations that never condense, after the quench converges rapidly and in an adiabatic way towards the new equilibrium value. The probability of fluctuations with $s>inf_t [s_c(t)]$, instead, displays a slow and more complex behavior, because the macroscopic population of the condensing degree of freedom is involved.
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We study the fluctuations of the Gaussian model, with conservation of the order parameter, evolving in contact with a thermal bath quenched from inverse temperature $beta _i$ to a final one $beta _f$. At every time there exists a critical value $s_c(t)$ of the variance $s$ of the order parameter per degree of freedom such that the fluctuations with $s>s_c(t)$ are characterized by a macroscopic contribution of the zero wavevector mode, similarly to what occurs in an ordinary condensation transition. We show that the probability of fluctuations with $s<inf_t [s_c(t)]$, for which condensation never occurs, rapidly converges towards a stationary behavior. By contrast, the process of populating the zero wavevector mode of the variance, which takes place for $s>inf _t [s_c(t)]$, induces a slow non-equilibrium dynamics resembling that of systems quenched across a phase transition.
We derive a simple formula for the fluctuations of the time average around the thermal mean for overdamped Brownian motion in a binding potential U(x). Using a backward Fokker-Planck equation, introduced by Szabo, et al. in the context of reaction kinetics, we show that for ergodic processes these finite measurement time fluctuations are determined by the Boltzmann measure. For the widely applicable logarithmic potential, ergodicity is broken. We quantify the large non-ergodic fluctuations and show how they are related to a super-aging correlation function.
Stochastic Langevin dynamics has been traditionally used as a tool to describe non-equilibrium processes. When utilized in systems with collective modes, traditional Langevin dynamics relaxes all modes indiscriminately, regardless of their wavelength. We propose a generalization of Langevin dynamics that can capture a differential coupling between collective modes and the bath, by introducing spatial correlations in the random forces. This allows modeling the electronic subsystem in a metal as a generalized Langevin bath endowed with a concept of locality, greatly improving the capabilities of the two-temperature model. The specific form proposed here for the spatial correlations produces physical wavevector- and polarization-dependency of the relaxation produced by the electron-phonon coupling in a solid. We show that the resulting model can be used for describing the path to equilibration of ions and electrons, and also as a thermostat to sample the equilibrium canonical ensemble. By extension, the family of models presented here can be applied in general to any dense system, solids, alloys and dense plasmas. As an example, we apply the model to study the non-equilibrium dynamics of an electron-ion two-temperature Ni crystal.
Dissipative particle dynamics (DPD) belongs to a class of models and computational algorithms developed to address mesoscale problems in complex fluids and soft matter in general. It is based on the notion of particles that represent coarse-grained portions of the system under study and allow, therefore, to reach time and length scales that would be otherwise unreachable from microscopic simulations. The method has been conceptually refined since its introduction almost twenty five years ago. This perspective surveys the major conceptual improvements in the original DPD model, along with its microscopic foundation, and discusses outstanding challenges in the field. We summarize some recent advances and suggests avenues for future developments.
We investigate the dissipative dynamics yielded by the Lindblad equation within the coexistence region around a first order phase transition. In particular, we consider an exactly-solvable fullyconnected quantum Ising model with n-spin exchange (n > 2) - the prototype of quantum first order phase transitions - and several variants of the Lindblad equations. We show that physically sound results, including exotic non-equilibrium phenomena like the Mpemba effect, can be obtained only when the Lindblad equation involves jump operators defined for each of the coexisting phases, whether stable or metastable.
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