No Arabic abstract
We present the first results of directional point-contact spectroscopy in high quality CaC6 samples both along the ab plane and in the c-axis direction. The superconducting order parameter Delta(0), obtained by fitting the Andreev-reflection (AR) conductance curves at temperatures down to 400 mK with the single-band 3D Blonder-Tinkham-Klapwijk model, presents two different distributions in the two directions of the main current injection, peaked at 1.35 and 1.71 meV, respectively. By ab-initio calculations of the AR conductance spectra, we show that the experimental results are in good agreement with the recent predictions of gap anisotropy in CaC6.
Point-contact tunneling on CaC$_6$ crystals reproducibly reveals superconducting gaps, $Delta$, of 2.3$pm$0.2 meV which are $sim$~40% larger than earlier reports. That puts CaC$_6$ into the class of very strong-coupled superconductors since 2$Delta$/kT$_csim$~4.6. Thus soft Ca phonons will be primarily involved in the superconductivity, a conclusion that explains the large Ca isotope effect found recently for CaC$_6$. Consistency among superconductor-insulator-normal metal (SIN), SIS and Andreev reflection (SN) junctions reinforces the intrinsic nature of this result.
Point-contact Andreev reflection spectroscopy (PCAR) has proven to be one of the most powerful tools in the investigation of superconductors, where it provides information on the order parameter (OP), a fundamental property of the superconducting state. In the past 20 years, successive improvements of the models used to analyze the spectra have continuously extended its capabilities, making it suited to study new superconductors with exotic properties such as anisotropic, nodal and multiple OPs. In Fe-based superconductors, the complex compound- and doping-dependent Fermi surface and the predicted sensitivity of the OP to fine structural details present unprecedent challenges for this technique. Nevertheless, we show here that PCAR measurements in Fe-based superconductors carried out so far have already greatly contributed to our understanding of these materials, despite some apparent inconsistencies that can be overcome if a homogeneous treatment of the data is used. We also demonstrate that, if properly extended theoretical models for Andreev reflection are used, directional PCAR spectroscopy can provide detailed information not only on the amplitude and symmetry of the OPs, but also on the nature of the pairing boson, and even give some hints about the shape of the Fermi surface.
The point-contact spectroscopy, in contrast to the tunneling spectrocopy, considers small electrical contacts with direct conductivity. In the normal state, it enables one to measure the spectral function of electron-boson interaction. In the superconducting state, new features appear connected with the energy dependence of excess current. The non-linearities of the current-voltage characteristic are due to: i) The inelastic scattering of electron quasiparticles in the contact region; ii) The energy dependence of the superconducting energy gap, and iii) The non-equilibrium superconducting effects. These effects are discussed from the experimental point of view
Comment on Large energy gaps in CaC6 from tunneling spectroscopy: possible evidence of strong-coupling superconductivity
Systematic studies of the NdFeAsOF superconducting energy gap via the point-contact Andreev-reflection (PCAR) spectroscopy are presented. The PCAR conductance spectra show at low temperatures a pair of gap-like peaks at about 4 - 7 mV indicating the superconducting energy gap and in most cases also a pair of humps at around 10 mV. Fits to the s-wave two-gap model of the PCAR conductance allowed to determine two superconducting energy gaps in the system. The energy-gap features however disappear already at T* = 15 to 20 K, much below the particular Tc of the junction under study. At T* a zero-bias conductance (ZBC) peak emerges, which at higher temperatures usually overwhelms the spectrum with intensity significantly higher than the conductance signal at lower temperatures. Possible causes of this unexpected temperature effect are discussed. In some cases the conductance spectra show just a reduced conductance around the zero-bias voltage, the effect persisting well above the bulk transition temperature. This indicates a presence of the pseudogap in the system.