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Register a new userHCOOH high resolution spectroscopy in the 9.18$mu$m region
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Franck Bielsa
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We report on higly accurate absolute frequency measurement against a femtosecond frequency comb of 6 saturated absorption lines of formic acid (HCOOH) with an accuracy of 1 kHz. We also report the frequency measurement of 17 other lines with an accuracy of 2 kHz. Those lines are in quasi coincidence with the 9R(36) to 9R(42) CO$_2$ laser emission lines and are probed either by a CO$_2$ or a widely tunable quantum cascade laser phase locked to a master CO$_2$ laser. The relative stability of two HCOOH stabilized lasers is characterized by a relative Allan deviation of 4.5 10$^{-12}$ $tau^{-1/2}$. They give suitable frequency references for H$_2^+$ Doppler free two-photon spectroscopy.
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We report on high-resolution and spatially-resolved spectra of Io in the 4.0 {mu}m region, recorded with the VLT/CRIRES instrument in 2008 and 2010, which provide the first detection of the { u}1 + { u}3 band of SO2 in Ios atmosphere. Data are analyzed to constrain the latitudinal, longitudinal, and diurnal distribution of Ios SO2 atmosphere as well as its characteristic temperature. equatorial SO2 column densities clearly show longitudinal asymmetry, but with a maximum of around 1.5e17 cm-2 at central meridian longitude L = 200-220 and a minimum of around 3e16 cm-2 at L = 285-300, the longitudinal pattern somewhat differs from earlier inferences from Ly {alpha} and thermal IR measurements. Within the accuracy of the measurements, no evolution of the atmospheric density from mid-2008 to mid-2010 can be distinguished. The decrease of the SO2 column density towards high latitude is apparent, and the typical latitudinal extent of the atmosphere found to be (+-) 40{deg} at half-maximum. The data show moderate diurnal variations of the equatorial atmosphere, which is evidence for a partially sublimation-supported atmospheric component. Compared to local noon, factor of 2 lower densities are observed around 40{deg} before and 80{deg} after noon. Best-fit gas temperatures range from 150 to 220 K, with a weighted mean value of 170 (+-) 20 K, which should represent the column-weighted mean kinetic temperature of Ios atmosphere. Finally, although the data include clear thermal emission due to Pillan (in outburst in July 2008) and Loki, no detectable enhancements in the SO2 atmosphere above these volcanic regions are found, with an upper limit of 4e16 cm-2 at Pillan and 1e17 cm-2 at Loki.
Originating from the weak interaction, parity violation in chiral molecules has been considered as a possible origin of the biohomochirality. It was predicted in 1974 but has never been observed so far. Parity violation should lead to a very tiny frequency difference in the rovibrational spectra of the enantiomers of a chiral molecule. We have proposed to observe this predicted frequency difference using the two photon Ramsey fringes technique on a supersonic beam. Promising candidates for this experiment are chiral oxorhenium complexes, which present a large effect, can be synthesized in large quantity and enantiopure form, and can be seeded in a molecular beam. As a first step towards our objective, a detailed spectroscopic study of methyltrioxorhenium (MTO) has been undertaken. It is an ideal test molecule as the achiral parent molecule of chiral candidates for the parity violation experiment. For the 187Re MTO isotopologue, a combined analysis of Fourier transform microwave and infrared spectra as well as ultra-high resolution CO2 laser absorption spectra enabled the assignment of 28 rotational lines and 71 rovibrational lines, some of them with a resolved hyperfine structure. A set of spectroscopic parameters in the ground and first excited state, including hyperfine structure constants, was obtained for the antisymmetric Re=O stretching mode of this molecule. This result validates the experimental approach to be followed once a chiral derivative of MTO will be synthesized, and shows the benefit of the combination of several spectroscopic techniques in different spectral regions, with different set-ups and resolutions. First high resolution spectra of jet-cooled MTO, obtained on the set-up being developed for the observation of molecular parity violation, are shown, which constitutes a major step towards the targeted objective.
We present an experimental and theoretical study of the absorption and emission spectra of Yb atoms in a solid Ne matrix at a resolution of 0.025 nm. Five absorption bands were identified as due to transitions from the $4f^{14}5d^06s^2 ^1!S_0$ ground state configuration to $4f^{14}5d^06s6p$ and $4f^{13}5d^16s^2$ configurations. The two lowest energy bands were assigned to outer-shell transitions to $6s6p ^3P_1$ and $^1P_1$ atomic states and displayed the structure of a broad doublet and an asymmetric triplet, respectively. The remaining three higher-frequency bands were assigned to inner-shell transitions to distinct $J=1$ states arising from the $4f^{13}5d^16s^2$ configuration and were highly structured with narrow linewidths. A classical simulation was performed to identify the stability and symmetry of possible trapping sites in the Ne crystal. It showed that the overarching 1+2 structure of the high frequency bands could be predominantly ascribed to crystal field splitting in the axial field of a 10-atom vacancy of $C_{4v}$ symmetry. Their prominent substructures were shown to be manifestations of phonon sidebands associated with the zero-phonon lines on each crystal field state. Unprecedented for a metal-rare gas system, resolution of individual phonon states on an allowed electronic transition was possible under excitation spectroscopy which reflects the semi-quantum nature of solid Ne. In contrast to the absorption spectra, emission spectra produced by steady-state excitation into the $^1P_1$ absorption band consisted of simple, unstructured fluorescence bands.
Frequency combs have triggered an impressive evolution of optical metrology across diverse regions of the electromagnetic spectrum, from the ultraviolet to the terahertz frequencies. An unexplored territory, however, remains in the region of vibrational bending modes, mostly due to the lack of single-mode lasers in the long-wavelength (LW) part of the mid-infrared (MIR) spectrum. We fill this gap through a purely MIR-based nonlinear laser source with tunability from 12.1 to 14.8 $mu$m, optical power up to 110 $mu$W, MHz-level linewidth and comb calibration. This enables the first example of bending modes metrology in this region, with the assessment of several CO$_2$-based frequency benchmarks with uncertainties down to 30 kHz, and the accurate study of the $ u_{11}$ band of benzene, which is a significant testbed for the resolution of the spectrometer. These achievements pave the way for LW-MIR metrology, rotationally-resolved studies and astronomic observations of large molecules, such as aromatic hydrocarbons.
We have fabricated and characterized a n-doped InSb Faraday isolator in the mid-IR range (9.2 $mu$m). A high isolation ratio of $approx$30 dB with a transmission over 80% (polarizer losses not included) is obtained at room temperature. Further possible improvements are discussed. A similar design can be used to cover a wide wavelength range (lambda ~ 7.5-30 $mu$m).
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