Many chemical compounds (bases, inorganic acids, salts) have been used to find a suitable
solvent for vanadium oxide And determine optimal conditions for its Dissolution.The best
of them was sodium hydroxide at 2M concentration. The solubility was
100% at 90 °C and
the solubilitys time was 30 min. The number of motor cycles was 800 cycles / min and the
liquid / solid ratio was 200 g / L.
In addition,the best amino protonadted compounds were used to precipitate vanadates from
their solutions (monoethanolamine, diphenylamine, hydrazine, hydroxide amine
hydrochloride, urea) with several inorganic acids (HCl, H2SO4, HNO3) and 1: 1 acid/base
was monoethanolamine protonated with concentrated sulfur acid .
Three organic phosphorous compounds containing bridge
with (PhO) phenoxide and (Ph) phenyl group, to be used as materials derived element
cadmium ion according to the (liquid - liquid) extraction method that apply to widely used
in the restoration
of metal ions operations starting from aqueous solutions in mining
operations to environmental applications, and identified some of the physical properties
(melting point, spectra UV, IR).
Photometric method was adopted to determine the concentrations, as it used the
solution of 2-Nitroso, 1- Naphthol to determine the concentrations of cadmium ion in the
aqueous phase after extraction and its concentrations in the organic phase based on the
difference between the concentrations of primitive prepared aqueous solution and the final
concentrations in the aqueous phase.
Distribution Ratio DCd was studied of the ion cadmium between the aqueous medium
of the acid solution of Sulfuric and central Organic Dilutions containing different
concentrations of the previous prepared organophosphorus compounds also was studied the
Distribution Ratio DCd of ion cadmium depending of changing of pH-values in aqueous
medium and central organic Includes fixed concentration from the previous prepared
organophosphorus compounds and registered the distribution of information focus
numerically and graphically.
In this research we have synthesized a new macrocyclic Schiff base (II)
containing nitrogen- oxygen donor atoms which was designed and synthesized
by reaction of: 1,4– bis (6',6'- methoxy -3- formyl phenyl)-1,4- dioxa butane (I).
Identification of
this macrocyclic schiff base: (II) 1,16- Diaza–[3,6;11,14-di
(6',6'- methoxy phenyl)]-7,10,19,22 - tetraoxa cyclo tetra icozane-15,1dien was
determined by (LC-MS) and spectroscopy (IR). The liquid- liquid extraction of
metal such as Zn2+, Pb2+ and Ni2+ from aqueous phase to organic phase which
doesn't in water. The effect of chloroform and dichloromethane as organic
solvents over the metal extractions was investigated at 25± 0.10C by using
atomic absorption Spectrometer and extraction percentage was calculated.
