To illustrate Boltzmanns construction of an entropy function that is defined for a single microstate of a system, we present here the simple example of the free expansion of a one dimensional gas of hard point particles. The construction requires one to define macrostates, corresponding to macroscopic observables. We discuss two different choices, both of which yield the thermodynamic entropy when the gas is in equilibrium. We show that during the free expansion process, both the entropies converge to the equilibrium value at long times. The rate of growth of entropy, for the two choice of macrostates, depends on the coarse graining used to define them, with different limiting behaviour as the coarse graining gets finer. We also find that for only one of the two choices is the entropy a monotonically increasing function of time. Our system is non-ergodic, non-chaotic and essentially non-interacting; our results thus illustrate that these concepts are not very relevant for the question of irreversibility and entropy increase. Rather, the notions of typicality, large numbers and coarse-graining are the important factors. We demonstrate these ideas through extensive simulations as well as analytic results.
It is very common in the literature to write down a Markovian quantum master equation in Lindblad form to describe a system with multiple degrees of freedom and weakly connected to multiple thermal baths which can, in general, be at different temperatures and chemical potentials. However, the microscopically derived quantum master equation up to leading order in system-bath coupling is of the so-called Redfield form which is known to not preserve complete positivity in most cases. We analytically show that, in such cases, enforcing complete positivity by imposing any Lindblad form, via any further approximation, necessarily leads to either violation of thermalization, or inaccurate coherences in the energy eigenbasis which then cause a violation of local conservation laws in the non-equilibrium steady state (NESS). In other words, a weak system-bath coupling quantum master equation that is completely positive, shows thermalization and preserves local conservation laws in NESS is fundamentally impossible in generic situations. On the other hand, the Redfield equation, although generically not completely positive, shows thermalization, always preserves local conservation laws and gives correct coherences to leading order. We exemplify our analytical results numerically in an interacting open quantum spin system.
We consider an active Brownian particle in a $d$-dimensional harmonic trap, in the presence of translational diffusion. While the Fokker-Planck equation can not in general be solved to obtain a closed form solution of the joint distribution of positions and orientations, as we show, it can be utilized to evaluate the exact time dependence of all moments, using a Laplace transform approach. We present explicit calculation of several such moments at arbitrary times and their evolution to the steady state. In particular we compute the kurtosis of the displacement, a quantity which clearly shows the difference of the active steady state properties from the equilibrium Gaussian form. We find that it increases with activity to asymptotic saturation, but varies non-monotonically with the trap-stiffness, thereby capturing a recently observed active- to- passive re-entrant behavior.
It is well known that path probabilities of Brownian motion correspond to the equilibrium configurational probabilities of flexible Gaussian polymers, while those of active Brownian motion correspond to in-extensible semiflexible polymers. Here we investigate the properties of the equilibrium polymer that corresponds to the trajectories of particles acted on simultaneously by both Brownian as well as active noise. Through this mapping we can see interesting crossovers in mechanical properties of the polymer with changing contour length. The polymer end-to-end distribution exhibits Gaussian behaviour for short lengths, which changes to the form of semiflexible filaments at intermediate lengths, to finally go back to a Gaussian form for long contour lengths. By performing a Laplace transform of the governing Fokker-Planck equation of the active Brownian particle, we discuss a direct method to derive exact expressions for all the moments of the relevant dynamical variables, in arbitrary dimensions. These are verified via numerical simulations and used to describe interesting qualitative features such as, for example, dynamical crossovers. Finally we discuss the kurtosis of the ABPs position which we compute exactly and show that it can be used to differentiate between active Brownian particles and active Ornstein-Uhlenbeck process.
We consider a one-dimensional gas of $N$ charged particles confined by an external harmonic potential and interacting via the one-dimensional Coulomb potential. For this system we show that in equilibrium the charges settle, on an average, uniformly and symmetrically on a finite region centred around the origin. We study the statistics of the position of the rightmost particle $x_{max}$ and show that the limiting distribution describing its typical fluctuations is different from the Tracy-Widom distribution found in the one-dimensional log-gas. We also compute the large deviation functions which characterise the atypical fluctuations of $x_{max}$ far away from its mean value. In addition, we study the gap between the two rightmost particles as well as the index $N_+$, i.e., the number of particles on the positive semi-axis. We compute the limiting distributions associated to the typical fluctuations of these observables as well as the corresponding large deviation functions. We provide numerical supports to our analytical predictions. Part of these results were announced in a recent Letter, Phys. Rev. Lett. 119, 060601 (2017).
We address the problem of transmission of electrons between two noninteracting leads through a region where they interact (quantum dot). We use a model of spinless electrons hopping on a one-dimensional lattice and with an interaction on a single bond. We show that all the two-particle scattering states can be found exactly. Comparisons are made with numerical results on the time evolution of a two-particle wave packet and several interesting features are found for scattering. For N particles the scattering state is obtained by perturbation theory. For a dot connected to Fermi seas at different chemical potentials, we find an expression for the change in the Landauer current resulting from the interactions on the dot. We end with some comments on the case of spin-1/2 electrons.
