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Gen Shirane began studying ferroelectrics while he was still based in Japan in the early 1950s. It was therefore natural that when he arrived at Brookhaven and began specialising in neutron scattering that he would devote much of his energy and expertise studying structural phase transitions. We review the ground breaking experiments that showed the behaviour of antiferroelectrics and ferroelectrics were reasonably described in terms of the soft mode concept of structural phase transitions. This work lead directly to Gen being awarded the Buckley prize and, jointly with John Axe, awarded the Warren prize. We then describe his work on incommensurate phase transitions and in particular how the giant Kohn anomalies are responsible for the structural instabilities in one-dimensional metals. Finally Gen carefully investigated the central peak and the two-length scale phenomena that occur at most if not all transitions. Due to Gens elegant experimental work we know a great deal about both of these effects but in neither case is theory able to explain all of his results
We describe here in detail the recently introduced methodology for simulation of structural transitions in crystals. The applications of the new scheme are illustrated on various kinds of crystals and the advantages with respect to previous schemes a
We investigate the structural and magnetic phase transitions in EuTi1-xNbxO3 with synchrotron powder X-ray diffraction (XRD), resonant ultrasound spectroscopy (RUS), and magnetization measurements. Upon Nb-doping, the Pm-3m to I4/mcm structural trans
Understanding the structural phase diagram of nano scale SrTiO3 has important implications on the basic physics and applications of the general class of transition metal oxide perovskites. Pressure dependent structural measurements on monodispersed n
Twinning in crystalline materials plays an important role in many transformation and deformation processes, where underlying mechanisms can be strongly influenced by the structural, energetic and kinetic properties of associated twin boundaries (TBs)
Neutron diffraction studies as a function of temperature on solid solutions of MnSe and MnTe in the Se rich region are presented. Interestingly as Te is doped in MnSe, the structural transformation to NiAs phase diminishes, both in terms of % fractio