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Orbital and spin chains in ZnV2O4

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 نشر من قبل Seunghun Lee
 تاريخ النشر 2003
  مجال البحث فيزياء
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Our powder inelastic neutron scattering data indicate that zvo is a system of spin chains that are three dimensionally tangled in the cubic phase above 50 K due to randomly occupied $t_{2g}$ orbitals of V$^{3+}$ ($3d^2$) ions. Below 50 K in the tetragonal phase, the chains become straight due to antiferro-orbital ordering. This is evidenced by the characteristic wave vector dependence of the magnetic structure factor that changes from symmetric to asymmetric at the cubic-to-tetragonal transition.

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