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تسجيل مستخدم جديدGranular-like behavior of molecular flow in constricted nanopores
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The fluid flow through porous media is described by Darcys law, while the fluid/wall interactions can be neglected. In nanopores, where adsorption dominates, Darcys extension has been made, but approaches able to describe flows in mesopores are still lacking. We show here that molecular flows through nano-constrictions is well described by Berverloos law, predicting the mass flow rate of granular material through macro-apertures. This molecular and granular analogy, allows to derive a relationship providing a theoretical framework for the molecular flow in disordered mesoporous systems.
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