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تسجيل مستخدم جديدPrestellar grain-surface origins of deuterated methanol in comet 67P/Churyumov-Gerasimenko
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Deuterated methanol is one of the most robust windows astrochemists have on the individual chemical reactions forming deuterium-bearing molecules and the physicochemical history of the regions where they reside. The first-time detection of mono- and di-deuterated methanol in a cometary coma is presented for comet 67P/Churyumov-Gerasimenko using Rosetta-ROSINA data. D-methanol (CH3OD and CH2DOH combined) and D2-methanol (CH2DOD and CHD2OH combined) have an abundance of 5.5+/-0.46 and 0.00069+/-0.00014 per cent relative to normal methanol. The data span a methanol deuteration fraction (D/H ratio) in the 0.71-6.6 per cent range, accounting for statistical corrections for the location of D in the molecule and including statistical error propagation in the ROSINA measurements. It is argued that cometary CH2DOH forms from CO hydrogenation to CH3OH and subsequent H-D substitution reactions in CH3-R. CHD2OH is likely produced from deuterated formaldehyde. Meanwhile, CH3OD and CH2DOD, could form via H-D exchange reactions in OH-R in the presence of deuterated water ice. Methanol formation and deuteration is argued to occur at the same epoch as D2O formation from HDO, with formation of mono-deuterated water, hydrogen sulfide, and ammonia occurring prior to that. The cometary D-methanol/methanol ratio is demonstrated to agree most closely with that in prestellar cores and low-mass protostellar regions. The results suggest that cometary methanol stems from the innate cold (10-20 K) prestellar core that birthed our Solar System. Cometary volatiles individually reflect the evolutionary phases of star formation from cloud to core to protostar.
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Dust is an important constituent in cometary comae; its analysis is one of the major objectives of ESAs Rosetta mission to comet 67P/Churyumov-Gerasimenko (C-G). Several instruments aboard Rosetta are dedicated to studying various aspects of dust in
the cometary coma, all of which require a certain level of exposure to dust to achieve their goals. At the same time, impacts of dust particles can constitute a hazard to the spacecraft. To conciliate the demands of dust collection instruments and spacecraft safety, it is desirable to assess the dust environment in the coma even before the arrival of Rosetta. We describe the present status of modelling the dust coma of 67P/C-G and predict the speed and flux of dust in the coma, the dust fluence on a spacecraft along sample trajectories, and the radiation environment in the coma. The model will need to be refined when more details of the coma are revealed by observations. An overview of astronomical observations of 67P/C-G is given and model parameters are derived from these data where possible. For quantities not yet measured for 67P/C-G, we use values obtained for other comets. One of the most important and most controversial parameters is the dust mass distribution. We summarise the mass distribution functions derived from the in-situ measurements at comet 1P/Halley in 1986. For 67P/C-G, constraining the mass distribution is currently only possible by the analysis of astronomical images. We find that the results from such analyses are at present rather heterogeneous, and we identify a need to find a model that is reconcilable with all available observations.
Molecular oxygen has been detected in the coma of comet 67P/Churyumov-Gerasimenko with abundances in the 1-10% range by the ROSINA-DFMS instrument on board the Rosetta spacecraft. Here we find that the radiolysis of icy grains in low-density environm
ents such as the presolar cloud may induce the production of large amounts of molecular oxygen. We also show that molecular oxygen can be efficiently trapped in clathrates formed in the protosolar nebula, and that its incorporation as crystalline ice is highly implausible because this would imply much larger abundances of Ar and N2 than those observed in the coma. Assuming that radiolysis has been the only O2 production mechanism at work, we conclude that the formation of comet 67P/Churyumov-Gerasimenko is possible in a dense and early protosolar nebula in the framework of two extreme scenarios: (1) agglomeration from pristine amorphous icy grains/particles formed in ISM and (2) agglomeration from clathrates that formed during the disks cooling. The former scenario is found consistent with the strong correlation between O2 and H2O observed in 67P/C-Gs coma while the latter scenario requires that clathrates formed from ISM icy grains that crystallized when entering the protosolar nebula.
Comets are thought to preserve almost pristine dust particles, thus providing a unique sample of the properties of the early solar nebula. The microscopic properties of this dust played a key part in particle aggregation during the formation of the S
olar System. Cometary dust was previously considered to comprise irregular, fluffy agglomerates on the basis of interpretations of remote observations in the visible and infrared and the study of chondritic porous interplanetary dust particles that were thought, but not proved, to originate in comets. Although the dust returned by an earlier mission has provided detailed mineralogy of particles from comet 81P/Wild, the fine-grained aggregate component was strongly modified during collection. Here we report in situ measurements of dust particles at comet 67P/Churyumov-Gerasimenko. The particles are aggregates of smaller, elongated grains, with structures at distinct sizes indicating hierarchical aggregation. Topographic images of selected dust particles with sizes of one micrometre to a few tens of micrometres show a variety of morphologies, including compact single grains and large porous aggregate particles, similar to chondritic porous interplanetary dust particles. The measured grain elongations are similar to the value inferred for interstellar dust and support the idea that such grains could represent a fraction of the building blocks of comets. In the subsequent growth phase, hierarchical agglomeration could be a dominant process and would produce aggregates that stick more easily at higher masses and velocities than homogeneous dust particles. The presence of hierarchical dust aggregates in the near-surface of the nucleus of comet 67P also provides a mechanism for lowering the tensile strength of the dust layer and aiding dust release.
Recent observations made by the Rosetta/ROSINA instrument have detected molecular oxygen in the coma of comet 67P/Churyumov-Gerasimenko with abundances at the 1-10% level relative to H2O. Previous studies have indicated that the likely origin of the
O2 may be surface chemistry of primordial (dark cloud) origin, requiring somewhat warmer, denser and extreme H-atom poor conditions than are usually assumed. In this study we propose a primordial gas-phase origin for the O2 which is subsequently frozen and effectively hidden until the ice mantles are sublimated in the comets coma. Our study presents results from a three-phase astrochemical model that simulates the chemical evolution of ices in the primordial dark cloud phase, its gravitational collapse, and evolution in the early protosolar nebula. We find that the O2 abundance can be produced and is fairly robust to the choice of the free parameters. Good matches for the O2:H2O ratio and, to a lesser extent, the N2:CO and CO:H2O ratios are obtained, but the models significantly over-produce N2. We speculate that the low value of N2:O2 that is observed is a consequence of the specific thermal history of the comet.
We use the gravitational instability formation scenario of cometesimals to derive the aggregate size that can be released by the gas pressure from the nucleus of comet 67P/Churyumov-Gerasimenko for different heliocentric distances and different volat
ile ices. To derive the ejected aggregate sizes, we developed a model based on the assumption that the entire heat absorbed by the surface is consumed by the sublimation process of one volatile species. The calculations were performed for the three most prominent volatile materials in comets, namely, H_20 ice, CO_2 ice, and CO ice. We find that the size range of the dust aggregates able to escape from the nucleus into space widens when the comet approaches the Sun and narrows with increasing heliocentric distance, because the tensile strength of the aggregates decreases with increasing aggregate size. The activity of CO ice in comparison to H_20 ice is capable to detach aggregates smaller by approximately one order of magnitude from the surface. As a result of the higher sublimation rate of CO ice, larger aggregates are additionally able to escape from the gravity field of the nucleus. Our model can explain the large grains (ranging from 2 cm to 1 m in radius) in the inner coma of comet 67P/Churyumov-Gerasimenko that have been observed by the OSIRIS camera at heliocentric distances between 3.4 AU and 3.7 AU. Furthermore, the model predicts the release of decimeter-sized aggregates (trail particles) close to the heliocentric distance at which the gas-driven dust activity vanishes. However, the gas-driven dust activity cannot explain the presence of particles smaller than ~1 mm in the coma because the high tensile strength required to detach these particles from the surface cannot be provided by evaporation of volatile ices. These smaller particles can be produced for instance by spin-up and centrifugal mass loss of ejected larger aggregates.
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