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Several authors have proposed out of equilibrium thermal engines models, allowing optimization processes involving a trade off between the power output of the engine and its dissipation. These operating regimes are achieved by using objective functions such as the ecological function ($EF$). In order to measure the quality of the balance between these characteristic functions, it was proposed a relationship where power output and dissipation are evaluated in the above mentioned $EF$-regime and they are compared with respect to its values at the regime of maximum power output. We called this relationship Compromise Function and only depends of a parameter that measures the quality of the compromise. Thereafter this function was used to select a value of the mentioned parameter to obtain the generalization of some different objective functions (generalizations of ecological function, omega function and efficient power), by demanding that these generalization parameters maximize the above mentioned functions. In this work we demonstrate that this function can be used directly as an objective function: the $P{Phi}$-Compromise Function ($C_{PPhi}$), also that the operation modes corresponding to the maximum Generalized Ecological Function, maximum Generalized Omega Function and maximum Efficient power output, are special cases of the operation mode of maximum $C_{PPhi}$, having the same optimum high reduced temperature, then the characteristic functions will be the same in any of the above three working regimes, independent of the algebraic complexity of each generalized function. These results are presented for two different models of an irreversible energy converter: a non-endoreversible and a totally irreversible, both with heat leakage.
Even though irreversibility is one of the major hallmarks of any real life process, an actual understanding of irreversible processes remains still mostly semiempirical. In this paper we formulate a thermodynamic uncertainty principle for irreversibl
The aim of this paper is to determine lost works in a molecular engine and compare results with macro (classical) heat engines. Firstly, irreversible thermodynamics are reviewed for macro and molecular cycles. Secondly, irreversible thermodynamics ap
For many real physico-chemical complex systems detailed mechanism includes both reversible and irreversible reactions. Such systems are typical in homogeneous combustion and heterogeneous catalytic oxidation. Most complex enzyme reactions include irr
The ultimate goal of physics is finding a unique equation capable of describing the evolution of any observable quantity in a self-consistent way. Within the field of statistical physics, such an equation is known as the generalized Langevin equation
The chi-criterion is defined as the product of the energy conversion efficiency and the heat absorbed per-unit-time by the working substance [de Tomas et al., Phys. Rev. E, 85 (2012) 010104(R)]. The chi-criterion for Feynman ratchet as a refrigerator