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Superconductivity with exotic properties has often been discovered in materials with a layered (two-dimensional) crystal structure. The low dimensionality affects the electronic structure of materials, which could realize a high transition temperature (Tc) and/or unconventional pairing mechanisms. Here, we report the superconductivity in a layered tin arsenide NaSn2As2. The crystal structure consists of (Sn2As2)2- bilayers, which is bound by van-der-Waals forces, separated by Na+ ions. Measurements of electrical resistivity and specific heat confirm the bulk nature of superconductivity of NaSn2As2 with Tc of 1.3 K. Our results propose that the SnAs layers will be a basic structure providing another universality class of a layered superconducting family, and it provides a new platform for the physics and chemistry of low-dimensional superconductors with lone pair electrons.
We grew the single crystals of the SnAs-based van der Waals (vdW)-type superconductor NaSn$_2$As$_2$ and systematically measured its resistivity, specific heat, and ultralow-temperature thermal conductivity. The superconducting transition temperature
Superconducting transition temperature (Tc) reported in SnAs-based layered compound NaSn$_2$As$_2$ varies from 1.2 to 1.6 K, implying that its superconductivity is critically sensitive to non-stoichiometry. Here, we demonstrate that Na-doping on the
Layered superconductors have provided some interesting fields in condensed matter physics owing to the low dimensionality of their electronic states. For example, the high-Tc (high transition temperature) cuprates and the Fe-based superconductors pos
We have employed a new route to synthesize single phase F-doped LaOFeAs compound and confirmed the superconductivity above 20 K in this Fe-based system. We show that the new superconductor has a rather high upper critical field of about 54 T. A clear
The recent discovery of superconductivity in NaSn$_2$As$_2$ with a van der Waals layered structure raises immediate questions on its pairing mechanism and underlying electronic structure. Here, we present measurements of the temperature-dependent mag