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Oxide interfaces play very important roles for the physical and chemical properties of nanostructured materials, such as an ionic conductivity, superconductivity, and magnetism. Gadolinia-doped Ceria (GDC) is commonly selected as the interlayer between (La,Sr)MnO3 and Y2O3-stabilized ZrO2 in fuel cells. The chemical expansions across the oxide interlayer were carefully examined at the atomic resolution in order to understand the cation diffusion and existence of oxygen deficiency at the interfaces.
The transport and magnetic properties of correlated La{0.53}Sr{0.47}MnO{3} ultrathin films, grown epitaxially on SrTiO{3}, show a sharp cusp at the structural transition temperature of the substrate. Using a combination of experiment and theory we sh
Solar thermochemical hydrogen production (STCH) is a renewable alternative to hydrogen produced using fossil fuels. While serial bulk experimental methods can accurately measure STCH performance, screening chemically complex materials systems for new
We report on the first Raman data of Cu substituted La(1-y)Sr(y)Mn(1-x)Cu(x)O3 (0 < x < 0.10 and 0.17 < y < 0.3, accordingly in order to have the same Mn(4+)/[Mn(4+)+Mn(3+)] ratio), collected in the frequency range 100-900 cm-1 and at room temperatur
We present measurements of the thermal expansion coefficient $alpha$ of polycrystalline RFeAsO (R = La,Ce,Pr,Sm,Gd). Anomalies at the magnetic ordering transitions indicate a significant magneto-elastic coupling and a negative pressure dependence of
The electronic properties of the Mn:GaSe interface, produced by evaporating Mn at room temperature on an epsilon-GaSe(0001) single crystal surface, have been studied by soft X-ray spectroscopies. Substitutional effects of Mn replacing Ga cations and