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We study the maximum efficiency of a Carnot cycle heat engine based on a small system. It is revealed that due to the finiteness of the system, irreversibility may arise when the working substance contacts with a heat bath. As a result, there is a working-substance-dependent correction to the usual Carnot efficiency, which is valid only when the working substance is in the thermodynamic limit. We derives a general and simple expression for the maximum efficiency of a Carnot cycle heat engine in terms of the relative entropy. This maximum efficiency approaches the usual Carnot efficiency asymptotically when the size of the working substance increases to the thermodynamic limit. Our study extends the Carnots result to cases with arbitrary size working substance and demonstrates the subtlety of thermodynamics in small systems.
We study the efficiency at maximum power, $eta^*$, of engines performing finite-time Carnot cycles between a hot and a cold reservoir at temperatures $T_h$ and $T_c$, respectively. For engines reaching Carnot efficiency $eta_C=1-T_c/T_h$ in the rever
We study a class of cyclic Brownian heat engines in the framework of finite-time thermodynamics. For infinitely long cycle times, the engine works at the Carnot efficiency limit producing, however, zero power. For the efficiency at maximum power, we
We study the possibility of achieving the Carnot efficiency in a finite-power underdamped Brownian Carnot cycle. Recently, it was reported that the Carnot efficiency is achievable in a general class of finite-power Carnot cycles in the vanishing limi
We present a unified perspective on nonequilibrium heat engines by generalizing nonlinear irreversible thermodynamics. For tight-coupling heat engines, a generic constitutive relation of nonlinear response accurate up to the quadratic order is derive
We report on several specific student difficulties regarding the Second Law of Thermodynamics in the context of heat engines within upper-division undergraduates thermal physics courses. Data come from ungraded written surveys, graded homework assign