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تسجيل مستخدم جديدUnusual magnetism of layered chromium sulfides MCrS2 (M=Li, Na, K, Ag, and Au)
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MCrS2 compounds (M=Li, Na, K, Cu, Ag, and Au) with triangular Cr layers show large variety of magnetic ground states ranging from 120-degree antiferromagnetic order of Cr spins in LiCrS2 to double stripes in AgCrS2, helimagnetic order in NaCrS2, and, finally, ferromagnetic Cr layers in KCrS2. On the base of ab-initio band structure calculations and an analysis of various contributions to exchange interactions between Cr spins we explain this tendency as originating from a competition between antiferromagnetic direct nearest-neighbor d-d exchange and ferromagnetic superexchange via S p states which leads to the change of the sign of the nearest neighbor interaction depending on the radius of a M ion. It is shown that other important interactions are the third-neighbor interaction in a layer and interlayer exchange. We suggest that strong magneto-elastic coupling is most probably responsible for multiferroic properties of at least one material of this family, namely, AgCrS2.
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