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We used the new IRAM 30-m FTS backend to perform an unbiased ~15 GHz wide survey at 3 mm toward the Pipe Nebula young diffuse starless cores. We found an unexpectedly rich chemistry. We propose a new observational classification based on the 3 mm molecular line emission normalized by the core visual extinction (Av). Based on this classification, we report a clear differentiation in terms of chemical composition and of line emission properties, which served to define three molecular core groups. The diffuse cores, Av<~15, show poor chemistry with mainly simple species (e.g. CS and CCH). The oxo-sulfurated cores, Av~15--22, appear to be abundant in species like SO and SO2, but also in HCO, which seem to disappear at higher densities. Finally, the deuterated cores, Av>~22, show typical evolved chemistry prior to the onset of the star formation process, with nitrogenated and deuterated species, as well as carbon chain molecules. Based on these categories, one of the diffuse cores (Core 47) has the spectral line properties of the oxo-sulfurated ones, which suggests that it is a possible failed core.
The Pipe Nebula is a massive, nearby dark molecular cloud with a low star-formation efficiency which makes it a good laboratory to study the very early stages of the star formation process. The Pipe Nebula is largely filamentary, and appears to be th
The Pipe nebula is a massive, nearby, filamentary dark molecular cloud with a low star-formation efficiency threaded by a uniform magnetic field perpendicular to its main axis. It harbors more than a hundred, mostly quiescent, very chemically young s
SWAS and Odin provided stringent upper limits on the gas phase water abundance of dark clouds (x(H2O) < 7x10^-9). We investigate the chemistry of water vapor in starless cores beyond the previous upper limits using the highly improved angular resolut
(Abridged) We present evidence that low-mass starless cores, the simplest units of star formation, are systematically differentiated in their chemical composition. Molecules including CO and CS almost vanish near the core centers, where the abundance
We report the first extragalactic detection of CF+, the fluoromethylidynium ion, in the z=0.89 absorber toward PKS1830-211. We estimate an abundance of ~3E-10 relative to H2 and that ~1% of fluorine is captured in CF+. The absorption line profile of