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Oxygen isotope effects in high-quality thin films of manganites: Quantitative constraints on the physics of manganites

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 نشر من قبل Guo-Meng Zhao
 تاريخ النشر 1999
  مجال البحث فيزياء
والبحث باللغة English
 تأليف G. M. Zhao




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Oxygen isotope effects on the transport properties have been studied in high-quality epitaxial thin films of La_{0.75}Ca_{0.25}MnO_{3} and Nd_{0.7}Sr_{0.3}MnO_{3}. In the paramagnetic state, the resistivity can be well fitted by rho (T) = (A/sqrt{T})exp(E_{rho}/k_{B}T) with the parameters A and E_{a} depending strongly on the oxygen isotope mass. The resistivity below 80 K almost perfectly follows rho = rho_{o}+ Bomega_{s}/sinh^{2}(hbaromega_{s}/2k_{B}T) with hbaromega_{s}/k_{B} sim 100 K. Both rho_{o} and B increase by about 15(3)% upon raplacing $^{16}$O by $^{18}$O. The results provide quantitative constraints on the basic physics of manganites.

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We report a study of oxygen isotope effects on low temperature specific heat, magnetization, and resistivity of La$_{1-x}$Ca$_{x}$MnO$_{3}$ and (La$_{1-y}$Pr$_{y})_{0.67}$Ca$_{0.33}$MnO$_{3}$. For the metallic compositions of La$_{1-x}$Ca$_{x}$MnO$_{ 3}$ and for charge-ordered La$_{0.5}$Ca$_{0.5}$MnO$_{3}$ no change in low temperature specific heat has been detected with $^{16}$O -$^{18}$O exchange, while compounds of (La$_{1-y}$Pr$_{y})_{0.67}$Ca$_{0.33}$MnO$_{3}$ (0.4<y<0.6) show a significant change in low temperature properties. The low temperature specific heat indicates a presence of the charge-ordered phase even in compositions of (La$_{1-y}$Pr$_{y})_{0.67}$Ca$_{0.33}$MnO$_{3}$ which are metallic at low temperatures. We suggest that the changes induced by the oxygen isotope exchange are caused by an increase of the charge-ordered phase in $^{18}$O samples.
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