اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدStatistical mechanics of double-stranded semi-flexible polymers
112
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
We study the statistical mechanics of double-stranded semi-flexible polymers using both analytical techniques and simulation. We find a transition at some finite temperature, from a type of short range order to a fundamentally different sort of short range order. In the high temperature regime, the 2-point correlation functions of the object are identical to worm-like chains, while in the low temperature regime they are different due to a twist structure. In the low temperature phase, the polymers develop a kink-rod structure which could clarify some recent puzzling experiments on actin.
قيم البحث
اقرأ أيضاً
We consider the unwinding of two lattice polymer strands of length N that are initially wound around each other in a double-helical conformation and evolve through Rouse dynamics. The problem relates to quickly bringing a double-stranded polymer well
above its melting temperature, i.e., the binding interactions between the strands are neglected, and the strands separate from each other as it is entropically favorable for them to do so. The strands unwind by rotating around each other until they separate. We find that the process proceeds from the ends inward; intermediate conformations can be characterized by a tightly wound inner part, from which loose strands are sticking out, with length l~t^0.39. The total time needed for the two strands to unwind scales as a power of N as tu~N^(2.57+-0.03). We present a theoretical argument, which suggests that during this unwinding process, these loose strands are far out of equilibrium.
Noethers calculus of invariant variations yields exact identities from functional symmetries. The standard application to an action integral allows to identify conservation laws. Here we rather consider generating functionals, such as the free energy
and the power functional, for equilibrium and driven many-body systems. Translational and rotational symmetry operations yield mechanical laws. These global identities express vanishing of total internal and total external forces and torques. We show that functional differentiation then leads to hierarchies of local sum rules that interrelate density correlators as well as static and time direct correlation functions, including memory. For anisotropic particles, orbital and spin motion become systematically coupled. The theory allows us to shed new light on the spatio-temporal coupling of correlations in complex systems. As applications we consider active Brownian particles, where the theory clarifies the role of interfacial forces in motility-induced phase separation. For active sedimentation, the center-of-mass motion is constrained by an internal Noether sum rule.
We consider self-propelled particles undergoing run-and-tumble dynamics (as exhibited by E. coli) in one dimension. Building on previous analyses at drift-diffusion level for the one-particle density, we add both interactions and noise, enabling disc
ussion of domain formation by self-trapping, and other collective phenomena. Mapping onto detailed-balance systems is possible in certain cases.
We show that near a second order phase transition in a two-component elastic medium of size L in two dimensions, where the local elastic deformation-order parameter couplings can break the inversion symmetry of the order parameter, the elastic moduli
i diverges with the variance of the local displacement fluctuations scaling as $[ln(L/a_0)]^{2/3}$ and the local displacement correlation function scaling as $[ln(r/a_0)]^{2/3}$ for weak inversion-asymmetryThe elastic constants can also vanish for system size exceeding a non-universal value, making the system unstable for strong asymmetry, where a 0 is a small-scale cut-off. We show that the elastic deformation-order parameter couplings can make the phase transition first order, when the elastic modulii do not diverge, but shows a jump proportional to the jump in the order parameter, across the transition temperature. For a bulk system, the elastic stiffness does not diverge for weak asymmetry, but can vanish across a second order transition giving instability for strong asymmetry, or displays jumps across a first order transition. In-vitro experiments on binary fluids embedded in a polymerized network, magnetic colloidal crystals or magnetic crystals could test these predictions.
We construct a minimalist model of RNA secondary-structure formation and use it to study the mapping from sequence to structure. There are strong, qualitative differences between two-letter and four or six-letter alphabets. With only two kinds of bas
es, there are many alternate folding configurations, yielding thermodynamically stable ground-states only for a small set of structures of high designability, i.e., total number of associated sequences. In contrast, sequences made from four bases, as found in nature, or six bases have far fewer competing folding configurations, resulting in a much greater average stability of the ground state.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
