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Kondo resonances and anomalous gate dependence of electronic conduction in single-molecule transistors

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 نشر من قبل Douglas Natelson
 تاريخ النشر 2005
  مجال البحث فيزياء
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We report Kondo resonances in the conduction of single-molecule transistors based on transition metal coordination complexes. We find Kondo temperatures in excess of 50 K, comparable to those in purely metallic systems. The observed gate dependence of the Kondo temperature is inconsistent with observations in semiconductor quantum dots and a simple single-dot-level model. We discuss possible explanations of this effect, in light of electronic structure calculations.

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