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We report the in-plane resistivity and magnetic susceptibility of the layered cobalt oxide Na$_{0.35}$CoO$_{2}{cdot}1.3$H$_{2}$O single crystal. The temperature dependence of the resistivity shows metallic behavior from room temperature to the superconducting transition temperature $T_{c}$ of 4.5 K. Sharp resistive transition, zero resistivity and almost perfect superconducting volume fraction below $T_{c}$ indicate the good quality and the bulk superconductivity of the single crystal. The upper critical field $H_{c2}$ and the coherence length $xi$ are obtained from the resistive transitions in magnetic field parallel to the c-axis and the $ab$-plane. The anisotropy of $xi$, $xi_{ab} / xi_{c} =$ 12 nm/1.3 nm $simeq$ 9.2, suggests that this material is considered to be an anisotropic three dimensional superconductor. In the field parallel to the $ab$-plane, $H_{c2}$ seems to be suppressed to the value of Pauli paramagnetic limit. It may indicate the spin singlet superconductivity in the cobalt oxide.
We have used electron and neutron powder diffraction to elucidate the structural properties of superconducting NaD. Our measurements show that our superconducting sample exhbits a number of supercells ranging from ${1/3}a^{*}$ to ${1/15}a^{*}$, but t
We have studied the superconducting phase diagram of NaHspace as a function of electronic doping, characterizing our samples both in terms of Na content $x$ and the Co valence state. Our findings are consistent with a recent report that intercalation
A weak magnetic order was found in a non-superconducting bilayered-hydrate Na$_{x}$CoO$_{2}cdot y$H$_{2}$O sample by a Co Nuclear Quadrupole Resonance (NQR) measurement. The nuclear spin-lattice relaxation rate divided by temperature $1/T_1T$ shows a
In order to investigate the role of the water molecules in Na$_{0.35}$CoO$_{2}cdot$1.3H$_{2}$O, we synthesized superconducting Na$_{0.35}$CoO$_{2}cdot$1.3H$_{2}$O and nonsuperconducting Na$_{0.35}$CoO$_{2}cdot$0.7H$_{2}$O, and measured their normal-s
High-energy (h$ u$ = 5.95 keV) synchrotron Photoemission spectroscopy (PES) is used to study bulk electronic structure of Na$_{0.35}$CoO$_{2}$.1.3H$_{2}$O, the layered superconductor. In contrast to 3-dimensional doped Co oxides, Co $it{2p}$ core lev