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Using one- and two-dimensional NMR spectroscopy applied to $^{13}$C spin-labeled (TMTTF)$_2$AsF$_6$ and (TMTTF)$_2$PF$_6$, we demonstrate the existence of an intermediate charge-ordered phase in the TMTTF family of charge-transfer salts. At ambient temperature, the spectra are characteristic of nuclei in equivalent environments, or molecules. Below a continuous charge-ordering transition temperature T$_{co}$, the spectra are explained by assuming there are two inequivalent molecules with unequal electron densities. The absence of an associated magnetic anomaly indicates only the charge degrees of freedom are involved and the lack of evidence for a structural anomaly suggests that charge/lattice coupling is too weak to drive the transition.
Charge-ordering phenomena have been highly topical over the last few years. A phase transition towards a charge ordered state has been observed experimentally in several classes of materials. Among them, many studies have been devoted to the family o
Using a combination of Density Functional Theory, mean-field analysis and exact diagonalization calculations we reveal the emergence of a dimerized charge ordered state in TMTTF$_2$-PF$_6$ organic crystal. The interplay between charge and spin order
We report results of high-resolution measurements of the emph{c$^*$}-axis expansivity ($alpha_{c^{*}}$) at the charge-ordering (CO) transition for the quasi-1D (TMTTF)$_{2}$X compounds with X = SbF$_6$ and Br and make a comparison with previous resul
High-resolution thermal expansion measurements have been performed for exploring the mysterious structureless transition in (TMTTF)$_{2}$X (X = PF$_{6}$ and AsF$_{6}$), where charge ordering at $T_{CO}$ coincides with the onset of ferroelectric order
(TMTTF)2AsF6 and (TMTTF)2SbF6 are both known to undergo a charge ordering phase transition, though their ground states are different. The ground state of the first is Spin-Peierls, and the second is an antiferromagnet. We study the effect of pressure