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We review and update some aspects of deuterium chemistry in the post-recombination Universe with particular emphasis on the formation and destruction of HD. We examine in detail the available theoretical and experimental data for the leading reactions of deuterium chemistry and we highlight the areas where improvements in the determination of rate coefficients are necessary to reduce the remaining uncertainties. We discuss the cooling properties of HD and the modifications to the standard cooling function introduced by the presence of the cosmological radiation field. Finally, we consider the effects of deuterium chemistry on the dynamical collapse of primordial clouds in a simple ``top-hat scenario, and we speculate on the minimum mass a cloud must have in order to be able to cool in a Hubble time.
High levels of deuterium fractionation in gas-phase molecules are usually associated with cold regions, such as prestellar cores. Significant fractionation ratios are also observed in hot environments such as hot cores or hot corinos, where they are
Deuterium abundances measured recently from QSO absorption-line systems lie in the range from 3 10^{-5} to 3 10^{-4}, which shed some questions on standard big bang theory. We show that this discordance may simply be an artifact caused by inadequate
The current status of extragalactic deuterium abundance is discussed using two examples of `low and `high D/H measurements. We show that the discordance of these two types of D abundances may be a consequence of the spatial correlations in the stocha
We report the discovery of deuterium absorption in the very metal-poor ([Fe/H] = -2.88) damped Lyman-alpha system at z_abs = 3.06726 toward the QSO SDSS J1358+6522. On the basis of 13 resolved D I absorption lines and the damping wings of the H I Lym
We report a reanalysis of a near-pristine absorption system, located at a redshift z_abs=2.52564 toward the quasar Q1243+307, based on the combination of archival and new data obtained with the HIRES echelle spectrograph on the Keck telescope. This a