اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدSpin-gap formation due to spin-Peierls instability in $pi$-orbital-ordered NaO$_2$
205
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
We have investigated the low-temperature magnetism of sodium superoxide (NaO$_{2}$), in which spin, orbital, and lattice degrees of freedom are closely entangled. The magnetic susceptibility shows anomalies at $T_{1}=220$ K and $T_{2}=190$ K, which correspond well to the structural phase transition temperatures, and a sudden decrease below $T_{3}=34$ K. At 4.2 K, the magnetization shows a clear stepwise anomaly around 30 T with a large hysteresis. In addition, the muon spin relaxation experiments indicate no magnetic phase transition down to $T=0.3$ K. The inelastic neutron scattering spectrum exhibits magnetic excitation with a finite energy gap. These results confirm that the ground state of NaO$_{2}$ is a spin-singlet state. To understand this ground state in NaO$_{2}$, we performed Raman scattering experiments. All the Raman-active libration modes expected for the marcasite phase below $T_{2}$ are observed. Furthermore, we find that several new peaks appear below $T_{3}$. This directly evidences the low crystal symmetry, namely, the presence of the phase transition at $T_{3}$. We conclude the singlet-ground state of NaO$_{2}$ due to the spin-Peierls instability.
قيم البحث
اقرأ أيضاً
Using {it ab initio} density functional theory and single-orbital Hubbard model calculations via the density matrix renormalization group method, we systematically studied the monolayer VOI$_2$ with a $3d^1$ electronic configuration. Our phonon calcu
lations indicate that the orthorhombic $Pmm2$ FE-II phase is the most likely ground state, involving a ferroelectric distortion along the $a$-axis and V-V dimerization along the $b$-axis. Specifically, the pseudo Jahn-Teller effect caused by the coupling between empty V ($d_{xz/yz}$ and $d_{3z^2-r^2}$) and O $2p$ states is proposed as the mechanism that stabilizes the ferroelectric distortion from the paraelectric phase. Moreover, the half-filled metallic $d_{xy}$ band displays a Peierls instability along the $b$-axis, inducing a V-V dimerization. We also found very short-range antiferromagnetic coupling along the V-V chain due to the formation of nearly-decoupled spin singlets in the ground state.
We study the ground state orbital ordering of $LaMnO_3$, at weak electron-phonon coupling, when the spin state is A-type antiferromagnet. We determine the orbital ordering by extending to our Jahn-Teller system a recently developed Peierls instabilit
y framework for the Holstein model [1]. By using two-dimensional dynamic response functions corresponding to a mixed Jahn-Teller mode, we establish that the $Q_2$ mode determines the orbital order.
We report high-pressure x-ray diffraction and magnetization measurements combined with ab-initio calculations to demonstrate that the high-pressure optical and transport transitions recently reported in TiOCl, correspond in fact to an enhanced Ti3+-T
i3+ dimerization existing already at room temperature. Our results confirm the formation of a metal-metal bond between Ti3+ ions along the b-axis of TiOCl, accompanied by a strong reduction of the electronic gap. The evolution of the dimerization with pressure suggests a crossover from the spin-Peierls to a conventional Peierls situation at high pressures.
We report an investigation of charge, spin and lattice effects in the spin-Peierls state of the organic compound MEM(TCNQ)$_2$. The 16.5 GHz dielectric function along the chain axis shows an enhancement below the spin-Peierls transition temperature n
ear 18 K consistent with the charge coupling to the elastic strain involved in the transition. The velocity of two elastic modes perpendicular to the chain axis presents anomalies at the transition which can be explained with a Landau free energy model including a linear-quadratic coupling energy term between the appropriate elastic strain $e$ and the spin-Peierls magnetic gap $Delta_q$. The analysis of the dielectric and elastic features aims toward an order parameter with an associated critical exponent $beta sim$ 0.36, which is similar to the three-dimensional behavior seen in other spin-Peierls materials. All these effects studied in a magnetic field up to 18 Teslas appear also compatible with a mean-field model of a quasi-one-dimensional spin-Peierls system.
Several spin systems with low dimensionality develop a spin-dimer phase within a molecular orbital below TS, competing with long-range antiferromagnetic order. Very often, preferential orbital occupancy and ordering are the actual driving force for d
imerization, as in the so-called orbitally-driven spin-Peierls compounds (MgTi2O4, CuIr2S4, La4Ru2O10, NaTiSi2O6, etc.). Through a microscopic analysis of the thermal conductivity k (T) in La4Ru2O10, we show that the orbital occupancy fluctuates rapidly above TS, resulting in an orbital-liquid state. The strong orbital-lattice coupling introduces dynamic bond-length fluctuations that scatter the phonons to produce a k (T) proportional to T (i.e. glass-like) above TS. This phonon-glass to phonon-crystal transition is shown to occur in other spin-dimer systems, like NaTiSi2O6, pointing to a general phenomenon.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
