اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدQuantum spin state transitions in spin-1 equilateral triangular lattice antiferromagnet Na$_2$BaNi(PO$_4$)$_2$
119
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
We have grown single crystals of Na$_2$BaNi(PO$_4$)$_2$, a new spin-1 equilateral triangular lattice antiferromagnet (ETLAF), and performed magnetic susceptibility, specific heat and thermal conductivity measurements at ultralow temperatures. The main results are (i) at zero magnetic field, Na$_2$BaNi(PO$_4$)$_2$ exhibits a magnetic ordering at 430 mK with a weak ferromagnetic moment along the $c$ axis. This suggests a canted 120$^circ$ spin structure, which is in a plane including the crystallographic $c$ axis due to the existence of an easy-axis anisotropy and ferromagnetically stacked along the $c$ axis; (ii) with increasing field along the $c$ axis, a 1/3 magnetization plateau is observed which means the canted 120$^circ$ spin structure is transformed to a up up down (UUD) spin structure. With even higher fields, the UUD phase further evolves to possible V and V phases; (iii) with increasing field along the $a$ axis, the canted 120$^circ$ spin structure is possibly transformed to a umbrella phase and a V phase. Therefore, Na$_2$BaNi(PO$_4$)$_2$ is a rare example of spin-1 ETLAF with single crystalline form to exhibit easy-axis spin anisotropy and series of quantum spin state transitions.
قيم البحث
اقرأ أيضاً
The most fascinating feature of certain two-dimensional (2D) gapless quantum spin liquid (QSL) is that their spinon excitations behave like the fermionic carriers of a paramagnetic metal. The spinon Fermi surface is then expected to produce a linear
increase of the thermal conductivity with temperature that should manifest via a residual value ($kappa_0/T$) in the zero-temperature limit. However, this linear in T behavior has been reported for very few QSL candidates. Here, we studied the ultralow-temperature thermal conductivity of an effective spin-1/2 triangular QSL candidate Na$_2$BaCo(PO$_4$)$_2$, which has an antiferromagnetic order at very low temperature ($T_N sim$ 148 mK), and observed a finite $kappa_0/T$ extrapolated from the data above $T_N$. Moreover, while approaching zero temperature, it exhibits series of quantum spin state transitions with applied field along the $c$ axis. These observations indicate that Na$_2$BaCo(PO$_4$)$_2$ possibly behaves as a gapless QSL with itinerant spin excitations above $T_N$ and its strong quantum spin fluctuations persist below $T_N$.
We report on high-field electron spin resonance (ESR) studies of magnetic excitations in the spin-1/2 triangular-lattice antiferromagnet Cs$_2$CuBr$_4$. Frequency-field diagrams of ESR excitations are measured for different orientations of magnetic f
ields up to 25 T. We show that the substantial zero-field energy gap, $Deltaapprox9.5$ K, observed in the low-temperature excitation spectrum of Cs$_2$CuBr$_4$ [Zvyagin $et~al.$, Phys. Rev. Lett. 112, 077206 (2014)], is present well above $T_N$. Noticeably, the transition into the long-range magnetically ordered phase does not significantly affect the size of the gap, suggesting that even below $T_N$ the high-energy spin dynamics in Cs$_2$CuBr$_4$ is determined by short-range-order spin correlations. The experimental data are compared with results of model spin-wave-theory calculations for spin-1/2 triangle-lattice antiferromagnet.
Cu(pz)$_2$(ClO$_4$)$_2$ (with pz denoting pyrazine C$_4$H$_4$N$_2$) is a two-dimensional spin-1/2 square-lattice antiferromagnet with $T_{mathrm{N}}$ = 4.24 K. Due to a persisting focus on the low-temperature magnetic properties, its room-temperature
structural and physical properties caught no attention up to now. Here we report a study of the structural features of Cu(pz)$_2$(ClO$_4$)$_2$ in the paramagnetic phase, up to 330 K. By employing magnetization, specific heat, $^{35}$Cl nuclear magnetic resonance, and neutron diffraction measurements, we provide evidence of a second-order phase transition at $T^{star}$ = 294 K, not reported before. The absence of a magnetic ordering across $T^{star}$ in the magnetization data, yet the presence of a sizable anomaly in the specific heat, suggest a structural order-to-disorder type transition. NMR and neutron-diffraction data corroborate our conjecture, by revealing subtle angular distortions of the pyrazine rings and of ClO$^-_4$ counteranion tetrahedra, shown to adopt a configuration of higher symmetry above the transition temperature.
Birnessite compounds are stable across a wide range of compositions that produces a remarkable diversity in their physical, electrochemical and functional properties. These are hydrated analogues of the magnetically frustrated, mixed-valent manganese
oxide structures, with general formula, NaxMnO2. Here we demonstrate that the direct hydration of layered rock-salt type a-NaMnO2, with the geometrically frustrated triangular lattice topology, yields the birnessite type oxide, Na0.36MnO2 0.2H2O, transforming its magnetic properties. This compound has a much-expanded interlayer spacing compared to its parent a-NaMnO2 compound. We show that while the parent a-NaMnO2 possesses a Neel temperature of 45 K as a result of broken symmetry in the Mn3+ sub-lattice, the hydrated derivative undergoes collective spin-freezing at 29 K within the Mn3+/Mn4+ sub-lattice. Scaling-law analysis of the frequency dispersion of the AC susceptibility, as well as the temperature-dependent, low-field DC magnetization confirm a cooperative spin-glass state of strongly interacting spins. This is supported by complementary spectroscopic analysis (HAADF-STEM, EDS, EELS) as well as by a structural investigation (high-resolution TEM, X-ray and neutron powder diffraction) that yield insights into the chemical and atomic structure modifications. We conclude that the spin-glass state in birnessite is driven by the spin-frustration imposed by the underlying triangular lattice topology that is further enhanced by the in-plane bond-disorder generated by the mixed-valent character of manganese in the layers.
Magnetic properties and magnetic structure of the Ba$_{2}$Mn(PO$_{4}$)$_{2}$ antiferromagnet featuring frustrated zigzag chains of $S=frac{5}{2}$ Mn$^{2+}$ ions are reported based on neutron diffraction, density-functional band-structure calculations
, as well as temperature- and field-dependent measurements of the magnetization and specific heat. A magnetic transition at $T_Nsimeq 5$,K marks the onset of the antiferromagnetic order with the propagation vector ${mathbf k} = (frac12, 0, frac12)$ and ordered moment of $4.33pm0.08~mu_B$/Mn$^{2+}$ at 1.5,K, pointing along the $c$ direction. Direction of the magnetic moment is chosen by the single-ion anisotropy, which is relatively weak compared to the isostructural Ni$^{2+}$ compound. Geometrical frustration has strong impact on thermodynamic properties of Ba$_2$Mn(PO$_4)_2$, but manifestations of the frustration are different from those in Ba$_2$Ni(PO$_4)_2$, where frustration by isotropic exchange couplings is minor, yet strong and competing single-ion anisotropies are present. A spin-flop transition is observed around 2.5,T. The evaluation of the magnetic structure from the ground state via the spin-flop state to the field-polarized ferromagnetic state has been revealed by a comprehensive neutron diffraction study as a function of magnetic field below $T_N$. Finally, a magnetic phase diagram in the $H-T$ plane is obtained.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
