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Comments on Thermodiffusion: The physico-chemical mechanics view. J. Chem. Phys. 154, 024112 (2021)

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 نشر من قبل Zi-Kui Liu
 تاريخ النشر 2021
  مجال البحث فيزياء
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 تأليف Zi-Kui Liu




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In a series of publications, Kocherginsky and Gruebele presented a systematic framework for chemical transport and thermodiffusion to predict the Soret coefficients from thermodynamics. A macroscopic derivation of the Onsager reciprocal relations without recourse to microscopic fluctuations or equations of motion was also discussed. Their important contributions and some confusions are discussed.



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