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Numerous models have been developed in the literature to simulate the thermomechanical behavior of amorphous polymer at large strain. These models generally show a good agreement with experimental results when the material is submitted to uniaxial loadings (tension or compression) or in case of shear loadings. However, this agreement is highly degraded when they are used in the case of combined load cases. A generalization of these models to more complex loads is scarce. In particular, models that are identified in tension or compression often overestimate the response in shear. One difficulty lies in the fact that 3D models must aggregate different physical modeling, described with different kinematics. This requires the use of transport operators complex to manipulate. In this paper, we propose a mechanical model for large strains, generalized in 3D, and precisely introducing the adequate transport operators in order to obtain an exact kinematic. The stress strain duality is validated in the writing of the power of internal forces. This generalized model is applied in the case of a polycarbonate amorphous polymers. The simulation results in tension/compression and shear are compared with the classical modeling and experimental results from the literature. The results highly improve the numerical predictions of the mechanical response of amorphous polymers submitted to any load case.
Molecular dynamic simulation enables one to correlate the evolution of the micro-structure with anisotropic stress when a material is subject to strain. The anisotropic stress due to a constant strain-rate load in a cross-linked polymer is primarily
We have created a flat piling of disks in a numerical experiment using the Distinct Element Method (DEM) by depositing them under gravity. In the resulting pile, we then measured increments in stress and strain that were associated with a small decre
Thermal conductivities (TCs) of the vast majority of amorphous polymers are in a very narrow range, 0.1 $sim$ 0.5 Wm$^{-1}$K$^{-1}$, although single polymer chains possess TC of orders-of-magnitude higher. Entanglement of polymer chains plays an impo
The structural properties of a linear polymer and its evolution in time have a strong bearing on its anisotropic stress response. The mean-square bond length and mean bond angle are the critical parameters that influence the time-varying stress devel
A full factorial design of experiments was used to study the effect of blend shear strain on the compaction process, relative density and strength of pharmaceutical tablets. The powder blends were subjected to different shear strain levels (integral