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We use the measured fluxes of polycyclic aromatic hydrocarbon (PAH) emission features at 6.2, 7.7, 8.6, 11.0 and 11.2 $mu$m in the reflection nebula NGC 2023 to carry out a principal component analysis (PCA) as a means to study previously reported variations in the PAH emission. We find that almost all of the variations (99%) can be explained with just two parameters -- the first two principal components (PCs). We explore the characteristics of these PCs and show that the first PC ($PC_{1}$), which is the primary driver of the variation, represents the amount of emission of a mixture of PAHs with ionized species dominating over neutral species. The second PC ($PC_{2}$) traces variations in the ionization state of the PAHs across the nebula. Correlations of the PCs with various PAH ratios show that the 6.2 and 7.7 $mu$m bands behave differently than the 8.6 and 11.0 $mu$m bands, thereby forming two distinct groups of ionized bands. We compare the spatial distribution of the PCs to the physical conditions, in particular to the strength of the radiation field, $G_{0}$, and the $G_{0}/n_{H}$ ratio and find that the variations in $PC_{2}$, i.e. the ionization state of PAHs are strongly affected by $G_{0}$ whereas the amount of PAH emission (as traced by $PC_{1}$) does not depend on $G_0$.
We examine polycyclic aromatic hydrocarbon (PAH), dust and atomic/molecular emission toward the Galactic bulge using Spitzer Space Telescope observations of four fields: C32, C35, OGLE and NGC 6522. These fields are approximately centered on (l, b) =
Context: PAHs are thought to be a ubiquitous and important dust component of the interstellar medium. However, the effects of their immersion in a hot (post-shock) gas have never before been fully investigated. Aims: We study the effects of energetic
Context: PAHs appear to be an ubiquitous interstellar dust component but the effects of shocks waves upon them have never been fully investigated. Aims: To study the effects of energetic (~0.01-1 keV) ion (H, He and C) and electron collisions on PAHs
We have examined polycyclic aromatic hydrocarbon (PAH) excitation in a sample of 25 nearby face-on spiral galaxies using the ratio of mid-infrared PAH emission to dust mass. Within 11 of the galaxies, we found that the PAH excitation was straightforw
Context: Cosmic rays are present in almost all phases of the ISM. PAHs and cosmic rays represent an abundant and ubiquitous component of the interstellar medium. However, the interaction between them has never before been fully investigated. Aims: To