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We report a search for the diatomic hydrides SiH, PH, and FeH along the line of sight toward the chemically rich circumstellar envelopes of IRC+10216 and VY Canis Majoris. These molecules are thought to form in high temperature regions near the photospheres of these stars, and may then further react via gas-phase and dust-grain interactions leading to more complex species, but have yet to be constrained by observation. We used the GREAT spectrometer on SOFIA to search for rotational emission lines of these molecules in four spectral windows ranging from 600 GHz to 1500 GHz. Though none of the targeted species were detected in our search, we report their upper limit abundances in each source and discuss how they influence the current understanding of hydride chemistry in dense circumstellar media. We attribute the non-detections of these hydrides to their compact source sizes, high barriers of formation, and proclivity to react with other molecules in the winds.
The recent detection of fullerene (C$_{60}$) in space and the positive assignment of five diffuse interstellar bands to C$_{60}^+$ reinforce the notion that fullerene-related compounds can be efficiently formed in circumstellar envelopes and be prese
High resolution maps of maser emission provide very detailed information on processes occurring in circumstellar envelopes of late-type stars. A particularly detailed picture of the innermost shells around AGB stars is provided by SiO masers. Conside
Ultraviolet (UV) photodissociation of CO controls the abundances and distribution of CO and its photodissociation products. This significantly influences the gas-phase chemistry in the circumstellar envelope (CSE) around evolved stars. A better under
Studies of the CO and HI radio emission of some evolved stars are presented using data collected by the IRAM Plateau de Bure interferometer and Pico Veleta telescope, the Nanc{c}ay Radio Telescope and the JVLA and ALMA arrays. Approximate axial symme
We study the evolved stellar population of the galaxy Sextans A. This galaxy is one of the lowest metallicity dwarfs in which variable asymptotic giant branch stars have been detected, suggesting that little metal enrichment took place during the pas